{"title":"一维[Mn(en)3]CdSb2Se5的溶剂热合成及表征","authors":"Lirong Zhang, Feiyan Qi, Muge Shele, E. Namila, Liming Qi, Menghe Baiyin","doi":"10.1007/s10870-022-00953-1","DOIUrl":null,"url":null,"abstract":"<div><p>One quaternary selenidoantimonate of [Mn(en)<sub>3</sub>]CdSb<sub>2</sub>Se<sub>5</sub> (<b>1</b>) (en = ethylenediamine) was prepared under 1,2-propanediamine condition by mild solvothermal method. Single-crystal X-ray diffraction analysis reveals that compound <b>1</b> crystallizes in the monoclinic space group <i>C</i>2/c. Its structure consists of infinite 1D [CdSb<sub>2</sub>Se<sub>5</sub>]<sub>n</sub><sup>2n−</sup> anionic chains and [Mn(en)<sub>3</sub>]<sup>2+</sup> cations. Meanwhile, “Z” shaped eight-membered [Cd<sub>2</sub>Sb<sub>2</sub>Se<sub>4</sub>] and six-membered [CdSb<sub>2</sub>Se<sub>3</sub>] rings are alternately found. As estimated from UV–Vis absorption spectrum, the band gap of <b>1</b> is 2.58 eV. Compound <b>1</b> also showed rapid response and excellent reproducibility based on photoelectric test. In addition, the magnetic and other properties of <b>1</b> were studied.</p><h3>Graphical Abstract</h3><p>The manuscript describes the synthesis, crystal structure, single-crystal X-ray diffraction, elemental analysis, photoelectric response, thermogravimetric analysis, magnetic properties, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy of [Mn(en)<sub>3</sub>]CdSb<sub>2</sub>Se<sub>5</sub>. The photoelectric response of compound <b>1</b> was explored, and a highly repetitive and stable photocurrent curve was found, indicating that <b>1</b> is a typical p-type semiconductor. In addition, the magnetism of compound <b>1</b> was also studied, which showed that <b>1</b> had antiferromagnetic behavior.</p><figure><div><div><div><picture><source><img></source></picture></div></div></div></figure></div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"53 1","pages":"145 - 151"},"PeriodicalIF":0.4000,"publicationDate":"2022-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Solvothermal Synthesis and Characterization of One-Dimensional [Mn(en)3]CdSb2Se5\",\"authors\":\"Lirong Zhang, Feiyan Qi, Muge Shele, E. Namila, Liming Qi, Menghe Baiyin\",\"doi\":\"10.1007/s10870-022-00953-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>One quaternary selenidoantimonate of [Mn(en)<sub>3</sub>]CdSb<sub>2</sub>Se<sub>5</sub> (<b>1</b>) (en = ethylenediamine) was prepared under 1,2-propanediamine condition by mild solvothermal method. Single-crystal X-ray diffraction analysis reveals that compound <b>1</b> crystallizes in the monoclinic space group <i>C</i>2/c. Its structure consists of infinite 1D [CdSb<sub>2</sub>Se<sub>5</sub>]<sub>n</sub><sup>2n−</sup> anionic chains and [Mn(en)<sub>3</sub>]<sup>2+</sup> cations. Meanwhile, “Z” shaped eight-membered [Cd<sub>2</sub>Sb<sub>2</sub>Se<sub>4</sub>] and six-membered [CdSb<sub>2</sub>Se<sub>3</sub>] rings are alternately found. As estimated from UV–Vis absorption spectrum, the band gap of <b>1</b> is 2.58 eV. Compound <b>1</b> also showed rapid response and excellent reproducibility based on photoelectric test. In addition, the magnetic and other properties of <b>1</b> were studied.</p><h3>Graphical Abstract</h3><p>The manuscript describes the synthesis, crystal structure, single-crystal X-ray diffraction, elemental analysis, photoelectric response, thermogravimetric analysis, magnetic properties, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy of [Mn(en)<sub>3</sub>]CdSb<sub>2</sub>Se<sub>5</sub>. The photoelectric response of compound <b>1</b> was explored, and a highly repetitive and stable photocurrent curve was found, indicating that <b>1</b> is a typical p-type semiconductor. In addition, the magnetism of compound <b>1</b> was also studied, which showed that <b>1</b> had antiferromagnetic behavior.</p><figure><div><div><div><picture><source><img></source></picture></div></div></div></figure></div>\",\"PeriodicalId\":615,\"journal\":{\"name\":\"Journal of Chemical Crystallography\",\"volume\":\"53 1\",\"pages\":\"145 - 151\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2022-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Crystallography\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10870-022-00953-1\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-022-00953-1","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Solvothermal Synthesis and Characterization of One-Dimensional [Mn(en)3]CdSb2Se5
One quaternary selenidoantimonate of [Mn(en)3]CdSb2Se5 (1) (en = ethylenediamine) was prepared under 1,2-propanediamine condition by mild solvothermal method. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the monoclinic space group C2/c. Its structure consists of infinite 1D [CdSb2Se5]n2n− anionic chains and [Mn(en)3]2+ cations. Meanwhile, “Z” shaped eight-membered [Cd2Sb2Se4] and six-membered [CdSb2Se3] rings are alternately found. As estimated from UV–Vis absorption spectrum, the band gap of 1 is 2.58 eV. Compound 1 also showed rapid response and excellent reproducibility based on photoelectric test. In addition, the magnetic and other properties of 1 were studied.
Graphical Abstract
The manuscript describes the synthesis, crystal structure, single-crystal X-ray diffraction, elemental analysis, photoelectric response, thermogravimetric analysis, magnetic properties, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy of [Mn(en)3]CdSb2Se5. The photoelectric response of compound 1 was explored, and a highly repetitive and stable photocurrent curve was found, indicating that 1 is a typical p-type semiconductor. In addition, the magnetism of compound 1 was also studied, which showed that 1 had antiferromagnetic behavior.
期刊介绍：
Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
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