4′-（N-（2-氰乙基）吡咯-2-基）-2,2′：6′，2〃-联吡啶

IF 0.6 Q4 CHEMISTRY, ORGANIC Molbank Pub Date : 2023-07-05 DOI:10.3390/m1689

J. Husson

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引用次数: 0

摘要

介绍了一种新的具有吡咯杂环和氰基的多官能化联吡啶分子的制备和表征。该新化合物是由KF/氧化铝催化的4′-（吡咯-2-基）-2,2′：6′，2〃-联吡啶Michael加成丙烯腈得到的。温和的反应条件使腈基团保持不变。通过NMR光谱（1H和13C）以及通过高分辨率质谱和红外光谱对标题化合物进行充分表征。

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4′-(N-(2-Cyanoethyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine

The preparation and characterization of a new multi-functionalized terpyridine molecule featuring a pyrrole heterocycle and a cyano group is described. This new compound was obtained via a KF/alumina-catalyzed Michael addition of 4′-(pyrrol-2-yl)-2,2′:6′,2″-terpyridine into acrylonitrile. The mild reaction conditions leave the nitrile group unaltered. The title compound was fully characterized via NMR spectroscopy (1H and 13C) as well as via high resolution mass spectrometry and infrared spectroscopy.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)