用短加工时间在VT1-0钛上制备等离子体电解涂层

IF 1.1 Q4 ELECTROCHEMISTRY Surface Engineering and Applied Electrochemistry Pub Date : 2023-09-04 DOI:10.3103/S1068375523040051
I. A. Kozlov, B. L. Krit, N. V. Morozova, M. V. Gerasimov, I. V. Suminov
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引用次数: 0

摘要

研究了在不添加硅酸盐的情况下,在硫酸镍碱性电解液中在VT1-0钛表面获得连续等离子电解质保护氧化膜的可能性。研究了等离子体电解氧化(PEO)制备的涂层在基体上和涂层在25%硫酸中破坏后的元素组成和微观结构。研究结果表明,在3-10 min的处理时间内,形成薄的(1-7 μm)连续PEO涂层是可能的。当PEO持续时间超过10 min时,在电解质中加入添加剂(如硫酸镍)是有效的。假设镍进入涂层主要是由于等离子体微弧的作用。注意到所得涂层在腐蚀性介质中的耐腐蚀性有限。对涂层在25%硫酸溶液中破坏后干燥残留物的元素组成进行分析,可以推断出这种涂层的腐蚀破坏具有电化学性质。
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Plasma-Electrolytic Coatings Obtained on VT1-0 Titanium with a Short Processing Time

The possibility of obtaining thin continuous plasma-electrolyte protective oxide coatings on VT1-0 titanium in a nickel sulfate alkaline electrolyte without the addition of silicates in the sparking mode was studied. The elemental composition and the microstructure of coatings manufactured via plasma electrolytic oxidation (PEO) both on the substrate and after the destruction of the coating in 25% sulfuric acid were studied. As a result of the research, a possibility of forming thin (1–7 μm) continuous PEO coatings, with a treatment duration of 3–10 min, respectively, was established. The introduction of additives (for example, nickel sulfate) into the electrolyte is effective when the duration of PEO is more than 10 min. It was supposed that nickel was incorporated into the coating mainly due to the action of plasma microarcs. The limited corrosion resistance of the resulting coatings in aggressive media was noted. An analysis of the elemental composition of the dry residues of the coating after destruction in a 25% sulfuric acid solution gives grounds to assume the electrochemical nature of the corrosion destruction of such coatings.

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来源期刊
Surface Engineering and Applied Electrochemistry
Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering
CiteScore
1.70
自引率
22.20%
发文量
54
审稿时长
6 months
期刊介绍: Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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