石英微丝分散优化

N. Tolypina, E. KHakhaleva, D. A. Tolypin
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引用次数: 0

摘要

介绍开发新一代混凝土的问题之一是确保水泥和精细添加剂混合物的合理粒度组成,以确保水泥系统中所有颗粒的堆积最密实。在这方面,考虑到石英填料的比表面积、粘合剂成分中的浓度和水固比,本文考虑了石英填料分散结构的优化。材料和方法。在研究中,使用了ZAO Belgorod水泥的硅酸盐水泥TSEM I 42.5 N(GOST 31108-2020)和细石英。抗压强度样品在PGM-100 MG4实验室压力机上进行测试。使用Analysette 22 NanoTec加激光衍射粒度分析仪测定填料的粒度组成。后果所进行的研究已经确定微分散填料的最佳剂量与混合物的比表面积和V/T密切相关。结果表明,随着石英填料分散度的增加,最佳用量范围减小,随着水固比的增加,最优用量范围变窄。阐述了结构形成对分散优化水泥体系性能的影响机理。随着填料比表面积的增长,填充粘结剂表面单位的比活性降低,同时水泥水合物相之间的结晶-凝聚键数量减少。结论所获得的实验数据证实,对于由混合粘结剂制成的水泥石,水固体比不亚于矿物添加剂的浓度,因此,降低混合水泥的V/T是获得给定强度的必要条件。
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Quartz microfill dispersion optimisation
Introduction. One of the problems of developing new generation concrete is to ensure the rational granulometric composition of a mixture of cement and fine additives to ensure the densest packing of all particles of the cement system. In this regard, the paper considers the optimization of the dispersed structure of quartz filler, taking into account its specific surface area, concentration in the composition of the binder and water-solid ratio.Materials and methods. In the studies, Portland cement TSEM I 42.5 N (GOST 31108-2020) of ZAO Belgorod Cement and fine quartz were used. The compressive strength samples were tested on a PGM-100 MG4 laboratory press. The granulometric composition of the fillers was determined using Analysette 22 NanoTec plus laser diffraction particle size analyzer.Results. The conducted studies have allowed to determine that the optimal dosages of microdispersion filler are closely related to the specific surface area and the V/T of the mixture. It is shown that with an increase in the dispersion of quartz filler, a decrease in the range of optimal dosages is observed, which narrows with an increase in the water-solid ratio. The mechanisms of structure formation affecting the properties of dispersed-optimized cement systems are described. With the growth of the specific surface of the filler, the specific activity of the unit of the surface of the filled binder decreases, which is accompanied by a decrease in the number of crystallizationcoagulation bonds between the hydrate phases of cement.Conclusion. The experimental data obtained confirm that for a cement stone made of a mixed binder, the watersolid ratio is no less significant than the concentration of a mineral additive, therefore, a decrease in the V/T of mixed cements is a necessary condition for achieving a given strength.
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