{"title":"突尼斯炼油厂苛性废水特性分析","authors":"Aymen Souilhi, Salma Besbes Hentati, Mohamed Rzaigui","doi":"10.1007/s13203-020-00257-5","DOIUrl":null,"url":null,"abstract":"<p>A heterogeneous spent soda effluent generated from Tunisian petroleum refineries has been filtrated and separated in four solid fractions with a particle diameter of 160 to 100, 100 to 40, 40 to 16 and 16 to 10?μm and the fifth one with diameters?<?10?μm obtained after total evaporation of the remained filtrate. Spectroscopic characterizations of the condensed phases by means of X-ray induced photoelectron and IR absorption, as well as pH-metry, potentiometry and stationary voltammetry at Ag<sub>2</sub>S/Ag electrode studies of the filtrate, show that the whole of the separated fractions contain Na<sub>2</sub>S, NaHS, C<sub>2</sub>H<sub>5</sub>SNa, Na<sub>2</sub>S<sub>2</sub>O<sub>3</sub>, Na<sub>2</sub>SO<sub>3</sub> and methyl, ethyl and propyl mercaptans.</p>","PeriodicalId":472,"journal":{"name":"Applied Petrochemical Research","volume":"11 1","pages":"39 - 47"},"PeriodicalIF":0.1250,"publicationDate":"2020-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13203-020-00257-5","citationCount":"0","resultStr":"{\"title\":\"Characterization of the Tunisian petroleum refineries caustic effluent\",\"authors\":\"Aymen Souilhi, Salma Besbes Hentati, Mohamed Rzaigui\",\"doi\":\"10.1007/s13203-020-00257-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A heterogeneous spent soda effluent generated from Tunisian petroleum refineries has been filtrated and separated in four solid fractions with a particle diameter of 160 to 100, 100 to 40, 40 to 16 and 16 to 10?μm and the fifth one with diameters?<?10?μm obtained after total evaporation of the remained filtrate. Spectroscopic characterizations of the condensed phases by means of X-ray induced photoelectron and IR absorption, as well as pH-metry, potentiometry and stationary voltammetry at Ag<sub>2</sub>S/Ag electrode studies of the filtrate, show that the whole of the separated fractions contain Na<sub>2</sub>S, NaHS, C<sub>2</sub>H<sub>5</sub>SNa, Na<sub>2</sub>S<sub>2</sub>O<sub>3</sub>, Na<sub>2</sub>SO<sub>3</sub> and methyl, ethyl and propyl mercaptans.</p>\",\"PeriodicalId\":472,\"journal\":{\"name\":\"Applied Petrochemical Research\",\"volume\":\"11 1\",\"pages\":\"39 - 47\"},\"PeriodicalIF\":0.1250,\"publicationDate\":\"2020-11-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s13203-020-00257-5\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Petrochemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13203-020-00257-5\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Petrochemical Research","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s13203-020-00257-5","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Characterization of the Tunisian petroleum refineries caustic effluent
A heterogeneous spent soda effluent generated from Tunisian petroleum refineries has been filtrated and separated in four solid fractions with a particle diameter of 160 to 100, 100 to 40, 40 to 16 and 16 to 10?μm and the fifth one with diameters?<?10?μm obtained after total evaporation of the remained filtrate. Spectroscopic characterizations of the condensed phases by means of X-ray induced photoelectron and IR absorption, as well as pH-metry, potentiometry and stationary voltammetry at Ag2S/Ag electrode studies of the filtrate, show that the whole of the separated fractions contain Na2S, NaHS, C2H5SNa, Na2S2O3, Na2SO3 and methyl, ethyl and propyl mercaptans.
期刊介绍：
Applied Petrochemical Research is a quarterly Open Access journal supported by King Abdulaziz City for Science and Technology and all the manuscripts are single-blind peer-reviewed for scientific quality and acceptance. The article-processing charge (APC) for all authors is covered by KACST. Publication of original applied research on all aspects of the petrochemical industry focusing on new and smart technologies that allow the production of value-added end products in a cost-effective way. Topics of interest include: • Review of Petrochemical Processes • Reaction Engineering • Design • Catalysis • Pilot Plant and Production Studies • Synthesis As Applied to any of the following aspects of Petrochemical Research: -Feedstock Petrochemicals: Ethylene Production, Propylene Production, Butylene Production, Aromatics Production (Benzene, Toluene, Xylene etc...), Oxygenate Production (Methanol, Ethanol, Propanol etc…), Paraffins and Waxes. -Petrochemical Refining Processes: Cracking (Steam Cracking, Hydrocracking, Fluid Catalytic Cracking), Reforming and Aromatisation, Isomerisation Processes, Dimerization and Polymerization, Aromatic Alkylation, Oxidation Processes, Hydrogenation and Dehydrogenation. -Products: Polymers and Plastics, Lubricants, Speciality and Fine Chemicals (Adhesives, Fragrances, Flavours etc...), Fibres, Pharmaceuticals.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
