Yuka Mineyama, Ko Yoneda, Y. Yamada, Masayuki Koikawa
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引用次数: 0
摘要
进行了校正。用直接法(SIR92)求解该结构，并用傅里叶技术展开。合成了非2021标题化合物[Ni(h1 - no 2) 2]·ch3 CN， [h2 L1-NO 2 = 2-[2-(羟甲基苯基)亚甲基]-4-硝基苯酚]，并用单晶x射线分析对其进行了表征。晶胞参数为a = 10.556(2)Å， b = 11.779(3)Å， c = 12.247(3)Å， α = 86.412(10)°，β = 71.135(8)°，γ = 73.009(8)°，V = 1377.2(5)Å 3, D calcd = 1.549 g/cm 3, Z = 2。5989个独立反射的R 1 [I > 2 σ (I)]和wR 2(所有数据)值分别为0.0362和0.1024。三叉戟配体与镍原子以聚合物的方式配位。
Synthesis and Crystal Structure of Bis{2-[(2-hydroxymethylphenyl)iminomethyl]-4-nitrophenolato}nickel(II) Monoacetonitrile
correction was applied. The structure was solved by direct methods (SIR92) and expanded using Fourier techniques. The non-2021 The title compound, [Ni(HL1–NO 2 ) 2 ]·CH 3 CN, [H 2 L1–NO 2 = 2-[2-(hydroxymethylphenyl)iminomethyl]-4-nitrophenol], was synthesized and characterized by single-crystal X-ray analysis. The compound crystallizes in the triclinic space group P 1 with cell parameters a = 10.556(2)Å, b = 11.779(3)Å, c = 12.247(3)Å, α = 86.412(10) ° , β = 71.135(8) ° , γ = 73.009(8) ° , V = 1377.2(5)Å 3 , D calcd = 1.549 g/cm 3 , Z = 2. The R 1 [ I > 2 σ ( I )] and wR 2 (all data) values are 0.0362 and 0.1024, respectively, for all 5989 independent reflections. The tridentate ligands coordinate to the nickel atom as a mer -manner.
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