耦合Cahn–Hilliard方程中的局部化态

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2021-07-01 DOI:10.1093/imamat/hxab026
Tobias Frohoff-Hülsmann;Uwe Thiele
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引用次数: 14

摘要

经典的Cahn–Hilliard(CH)方程对应于描述二元混合物中相分解的梯度动力学模型。在旋节区,最初的均匀状态通过大规模的不稳定性自发分解为典型结构长度的液滴、空穴或迷宫式的浓度模式,随后是持续的粗化过程。在这里,我们考虑了两个浓度场的耦合CH动力学,并表明非互易(或主动或非变分)耦合可能导致小规模(图灵)不稳定性。在相应的主分叉处,出现了一个周期性模式稳态的分支。此外,存在由与均匀背景共存的图案化斑块组成的局部状态。稳态宇称对称和宇称非对称定域态的分支形成了具有守恒定律的系统典型的倾斜同宿蛇形结构。与具有梯度动力学的系统中的蛇形结构相反,在这里,Hopf不稳定性发生在足够大的活动下,这导致振荡和行进的局域模式。
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Localized states in coupled Cahn–Hilliard equations
The classical Cahn–Hilliard (CH) equation corresponds to a gradient dynamics model that describes phase decomposition in a binary mixture. In the spinodal region, an initially homogeneous state spontaneously decomposes via a large-scale instability into drop, hole or labyrinthine concentration patterns of a typical structure length followed by a continuously ongoing coarsening process. Here, we consider the coupled CH dynamics of two concentration fields and show that non-reciprocal (or active or non-variational) coupling may induce a small-scale (Turing) instability. At the corresponding primary bifurcation, a branch of periodically patterned steady states emerges. Furthermore, there exist localized states that consist of patterned patches coexisting with a homogeneous background. The branches of steady parity-symmetric and parity-asymmetric localized states form a slanted homoclinic snaking structure typical for systems with a conservation law. In contrast to snaking structures in systems with gradient dynamics, here, Hopf instabilities occur at a sufficiently large activity, which results in oscillating and travelling localized patterns.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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