香港利用木质纤维素废料生产汽油的经济可行性

Weixiang Guan, Sim-Ying Chua, Chi-Wing Tsang, Xiao Chen, Carol Sze Ki Lin, Raymond Sze Wai Fu, Haoquan Hu, Changhai Liang
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引用次数: 2

摘要

在本研究中,开发了概念性的工艺流程,并通过考虑几种有前途的木质素解聚实验工艺,如加氢脱氧和氢解,以及木质纤维素生物质分馏工艺,分析了木质生物质转化为生物燃料作为原料的经济可行性。利用SuperPro Designer?实现木质纤维素生物质商业化生产生物汽油的工程模拟过程。被建模。评估了最终产品与现行汽油规格的兼容性,并研究了各种混合方案,以满足产品的辛烷值和Reid蒸气压要求。从经济角度对模拟工程过程的经济潜力进行了评价。对三种不同催化体系的运行成本和资本投资进行了估算和讨论,以评估木质生物质增值过程的商业化潜力。确定了主要的潜在市场,包括木糖和纤维素纸浆等工艺副产品。从经济评价研究中发现,单独销售生物质分馏产品确实比木质素增值生产生物汽油有更大的利润,如果在香港设立工厂,在相同的投资回报率下,净现值分别为22,65.3万元和17.7万元。研究还发现,在增值过程中,催化剂在决定盈利能力方面起着关键作用,这不仅是因为催化剂的价格,还因为不同类型催化剂所获得的产品分布。为了获得相同的毛利润,使用铂催化剂的生物汽油的销售价格必须比使用钌催化剂的销售价格高近10倍。因此,催化剂的开发和工艺的改进是建立生物基循环经济的关键。
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Economic feasibility of gasoline production from lignocellulosic wastes in Hong Kong

In this study, the conceptual process flowsheet was developed and the economic feasibility of woody biomass conversion to biofuel as feedstock was analysed by considering several promising experimental processes for lignin depolymerization, such as hydrodeoxygenation and hydrogenolysis, along with lignocellulosic biomass fractionation processes. The engineering simulation process toward the commercial production of bio-gasoline from lignocellulosic biomass using SuperPro Designer? was modeled. The compatibility of the end products with the current gasoline specifications was evaluated and various blending options were investigated to meet the octane number and Reid vapor pressure requirement of the product. The economic potential of the simulated engineering process was then evaluated from an economic perspective. The operating costs and capital investment of three scenario using three different catalytic systems were estimated and discussed to assess of the potential of commercializing of woody biomass valorization process. The main potential market segments were identified, including the process by-products such as xylose and cellulose pulp. From the economic evaluation study, it was found that selling the biomass fractionation products alone does have a greater profit than valorization of lignin to produce bio-gasoline, with net present value of RMB 22,653,000 and RMB 177,000, respectively at the same return on investment if the plant is set up in Hong Kong. It was also found that catalysts play a pivotal role in determination of the profitability in the valorization process, not only because of the price of the catalyst, but also the product distributions obtained with various types of it. To obtain the same gross profit, the sale price of bio-gasoline has to be set higher with platinum catalysts than with ruthenium catalysts (nearly 10 folds). Thus, catalyst development and process improvement are crucial in the establishment of bio-based circular economy.

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