电化学、镍催化的C−C键形成的最新进展

IF 2.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Israel Journal of Chemistry Pub Date : 2023-07-27 DOI:10.1002/ijch.202300089
Mareena C. Franke, Daniel J. Weix
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引用次数: 0

摘要

镍催化的交叉亲电偶联(XEC)是形成碳-碳键的有效方法,已成为构建复杂分子的重要工具。虽然 XEC 最常用的是化学计量金属还原剂,但这些转化也可以通过电化学来驱动。电化学 XEC(eXEC)之所以具有吸引力,是因为它可以提高 XEC 的绿色环保性,而这一潜力已在近年来取得了众多进展。本综述的重点是 2010 年以来报道的电化学镍催化碳碳键形成反应,并按阳极半反应类型进行分类:牺牲阳极、牺牲还原剂和收敛配对电解。重点介绍了主要进展,并讨论了对更多可扩展方案的需求。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent Advances in Electrochemical, Ni-Catalyzed C−C Bond Formation

Nickel-catalyzed cross-electrophile coupling (XEC) is an efficient method to form carbon-carbon bonds and has become an important tool for building complex molecules. While XEC has most often used stoichiometric metal reductants, these transformations can also be driven electrochemically. Electrochemical XEC (eXEC) is attractive because it can increase the greenness of XEC and this potential has resulted in numerous advances in recent years. The focus of this review is on electrochemical, Ni-catalyzed carbon-carbon bond forming reactions reported since 2010 and is categorized by the type of anodic half reaction: sacrificial anode, sacrificial reductant, and convergent paired electrolysis. The key developments are highlighted and the need for more scalable options is discussed.

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来源期刊
Israel Journal of Chemistry
Israel Journal of Chemistry 化学-化学综合
CiteScore
6.20
自引率
0.00%
发文量
62
审稿时长
6-12 weeks
期刊介绍: The fledgling State of Israel began to publish its scientific activity in 1951 under the general heading of Bulletin of the Research Council of Israel, which quickly split into sections to accommodate various fields in the growing academic community. In 1963, the Bulletin ceased publication and independent journals were born, with Section A becoming the new Israel Journal of Chemistry. The Israel Journal of Chemistry is the official journal of the Israel Chemical Society. Effective from Volume 50 (2010) it is published by Wiley-VCH. The Israel Journal of Chemistry is an international and peer-reviewed publication forum for Special Issues on timely research topics in all fields of chemistry: from biochemistry through organic and inorganic chemistry to polymer, physical and theoretical chemistry, including all interdisciplinary topics. Each topical issue is edited by one or several Guest Editors and primarily contains invited Review articles. Communications and Full Papers may be published occasionally, if they fit with the quality standards of the journal. The publication language is English and the journal is published twelve times a year.
期刊最新文献
Cover Picture: (Isr. J. Chem. 8-9/2024) Special Issue on RNA-Based Catalysts that Revolutionized the Discovery of Bioactive Peptides Hexagonal and Trigonal Quasiperiodic Tilings Breaking the Degeneracy of Sense Codons – How Far Can We Go? Cover Picture: (Isr. J. Chem. 6-7/2024)
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