催化裂化废催化剂对炼油模拟废水中铅离子的吸附研究

A. Abubakar, Ijai Ezekiel Waba, S. Yunusa, Z. S. Gano
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引用次数: 1

摘要

各种工业废水处理不当造成环境污染。因此,本研究涉及使用再活化的FCC废催化剂,这是一种廉价可靠的吸附剂,用于从炼油厂模拟废水中去除Pb2+。采用响应面法(RSM)确定最佳操作条件。在温度、pH、吸附剂用量、接触时间等条件下,考察了废催化裂化催化剂的吸附性能。研究结束时,发现去除Pb2+的最佳条件为pH = 7,吸附剂用量1.75 g,接触时间75 min,温度117℃。在此条件下,Pb2+的最大去除率为100%。通过RSM下的中心复合设计,建立了二次模型方程来预测所有输入参数中Pb2+的去除。f统计值表明,温度对Pb2+的去除率影响最大,吸附剂用量和接触时间也有显著影响。
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Use of Reactivated Spent FCC Catalyst as Adsorbent for Lead (II) Ions from Refinery-based Simulated Wastewater
Improper handling of wastewater from various industries causes environmental pollution. Hence, this study involved using a reactivated spent FCC catalyst, a cheap and reliable adsorbent for Pb2+ removal from refinery-based simulated wastewater. In contrast, response surface methodology (RSM) was used to determine the optimum operating condition. The adsorptive capacity of the reactivated spent FCC catalyst was observed using different parameters such as temperature, pH, adsorbent dosage, and contact time. At the end of the study, it was found that the optimum condition for removing Pb2+ was at pH of 7, adsorbent dose of 1.75 g, contact time of 75 mins, and temperature of 117 oC. At this condition, the maximum removal efficiency of Pb2+ was found to be 100 %. A quadratic model equation via central composite design under the RSM was developed to predict the Pb2+ removal from all the input parameters. Based on the F-statistic values, the temperature had the greatest influence on the removal of Pb2+ while adsorbent dosage and contact time were also significant.  
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审稿时长
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