邻菲罗啉衍生物与己二酸的新型二维超分子铅配位聚合物的合成与结构表征

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2021-01-01 DOI:10.1515/mgmc-2021-0025

Yufei Song, Yu Yan, Hua Zhang, Xiuyan Wang

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引用次数: 3

摘要

摘要以1-（1H-咪唑并[4,5-f][1,10]菲咯啉-2-基）萘-2-醇（HL）和己二酸（H2adip）为原料，在水热条件下合成了一种新型金属有机配位聚合物[Pb（L）（adip）0.5]（1）。通过衍射和元素分析对配合物1进行了表征。在配合物1中，双核[Pb2L2]单元是通过OH去质子化桥接相邻的Pb（II）原子而形成的，己二酸酯连接双核[Pb2L2]单元以形成对称的一维链。通过L配体之间的π-π相互作用，1D链进一步延伸到2D超分子层结构。

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Synthesis and structural characterization of a novel 2D supramolecular lead coordination polymer with phenanthroline derivate and adipic acid

Abstract A new metal-organic coordination polymer, [Pb(L)(adip)0.5] (1) was synthesized under hydrothermal conditions by using 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (HL) and adipic acid (H2adip). The complex 1 was characterized by diffraction and elemental analyses. In complex 1, the binuclear [Pb2L2] units were formed by the OH-deprotonation bridging neighboring Pb(II) atoms, and the adipate linked the binuclear [Pb2L2] units to form a symmetric one-dimensional chain. The 1D chain was further extended to the 2D supramolecular layer structure through π-π interactions between the L ligands.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.