Edison Matamala-Cea, Luciano Becerra-Pino, Walter A. Rabanal-León, Rodrigo Arancibia, Paulina I. Hidalgo, Claudio A. Jiménez, Néstor Novoa
{"title":"偶极Y(III)基单卟啉酸盐配合物的制备:常规与微波辅助反应及理论红外研究","authors":"Edison Matamala-Cea, Luciano Becerra-Pino, Walter A. Rabanal-León, Rodrigo Arancibia, Paulina I. Hidalgo, Claudio A. Jiménez, Néstor Novoa","doi":"10.1007/s10847-022-01148-z","DOIUrl":null,"url":null,"abstract":"<div><p>The dissymmetrical and dipolar Y(III) complex <b>2</b> and its cationic precursor <b>1</b>, containing the proligands 5,10,15,20-tetrakis(4-bromophenyl)porphyrin <b>L1</b> and 1-anisyl-1,3-butanedione <b>L2</b>, were synthesized at fairly high yields, ranging from 40 to 78%, by conventional and microwave-assisted techniques, and were isolated as a microcrystalline compound. The products obtained in each case were characterized by <sup>1</sup>H-NMR, mass spectrometry, elemental analysis, Med-IR and Far-IR. The IR information collected shows good agreement with respect to the density functional theory (DFT) calculations carried out, validating the molecular geometry in each case. This innovative one-pot microwave-based method contributes an efficient pathway for obtaining challenging molecular architectures based on monoporphyrinate complexes without Diglyme.</p></div>","PeriodicalId":54324,"journal":{"name":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2022-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10847-022-01148-z.pdf","citationCount":"0","resultStr":"{\"title\":\"Preparation of dipolar Y(III)-based monoporphyrinate complexes: conventional vs microwave-assisted reaction and theoretical IR study\",\"authors\":\"Edison Matamala-Cea, Luciano Becerra-Pino, Walter A. Rabanal-León, Rodrigo Arancibia, Paulina I. Hidalgo, Claudio A. Jiménez, Néstor Novoa\",\"doi\":\"10.1007/s10847-022-01148-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The dissymmetrical and dipolar Y(III) complex <b>2</b> and its cationic precursor <b>1</b>, containing the proligands 5,10,15,20-tetrakis(4-bromophenyl)porphyrin <b>L1</b> and 1-anisyl-1,3-butanedione <b>L2</b>, were synthesized at fairly high yields, ranging from 40 to 78%, by conventional and microwave-assisted techniques, and were isolated as a microcrystalline compound. The products obtained in each case were characterized by <sup>1</sup>H-NMR, mass spectrometry, elemental analysis, Med-IR and Far-IR. The IR information collected shows good agreement with respect to the density functional theory (DFT) calculations carried out, validating the molecular geometry in each case. This innovative one-pot microwave-based method contributes an efficient pathway for obtaining challenging molecular architectures based on monoporphyrinate complexes without Diglyme.</p></div>\",\"PeriodicalId\":54324,\"journal\":{\"name\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2022-06-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s10847-022-01148-z.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inclusion Phenomena and Macrocyclic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10847-022-01148-z\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10847-022-01148-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation of dipolar Y(III)-based monoporphyrinate complexes: conventional vs microwave-assisted reaction and theoretical IR study
The dissymmetrical and dipolar Y(III) complex 2 and its cationic precursor 1, containing the proligands 5,10,15,20-tetrakis(4-bromophenyl)porphyrin L1 and 1-anisyl-1,3-butanedione L2, were synthesized at fairly high yields, ranging from 40 to 78%, by conventional and microwave-assisted techniques, and were isolated as a microcrystalline compound. The products obtained in each case were characterized by 1H-NMR, mass spectrometry, elemental analysis, Med-IR and Far-IR. The IR information collected shows good agreement with respect to the density functional theory (DFT) calculations carried out, validating the molecular geometry in each case. This innovative one-pot microwave-based method contributes an efficient pathway for obtaining challenging molecular architectures based on monoporphyrinate complexes without Diglyme.
期刊介绍:
The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites.
The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.