偶极Y(III)基单卟啉酸盐配合物的制备:常规与微波辅助反应及理论红外研究

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2022-06-06 DOI:10.1007/s10847-022-01148-z
Edison Matamala-Cea, Luciano Becerra-Pino, Walter A. Rabanal-León, Rodrigo Arancibia, Paulina I. Hidalgo, Claudio A. Jiménez, Néstor Novoa
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引用次数: 0

摘要

采用常规和微波辅助技术,合成了不对称偶极Y(III)配合物2及其阳离子前体1,其前置配体为5,10,15,20-四(4-溴苯基)卟啉L1和1-茴香基-1,3-丁二酮L2,产率在40% ~ 78%之间,并分离得到微晶化合物。通过1H-NMR、质谱、元素分析、mid - ir和Far-IR对所得产物进行了表征。所收集的红外信息与所进行的密度泛函理论(DFT)计算显示出良好的一致性,验证了每种情况下的分子几何形状。这种创新的一锅微波方法为获得具有挑战性的分子结构提供了一种有效的途径,这种分子结构基于单卟啉酸配合物,不含双lyme。
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Preparation of dipolar Y(III)-based monoporphyrinate complexes: conventional vs microwave-assisted reaction and theoretical IR study

The dissymmetrical and dipolar Y(III) complex 2 and its cationic precursor 1, containing the proligands 5,10,15,20-tetrakis(4-bromophenyl)porphyrin L1 and 1-anisyl-1,3-butanedione L2, were synthesized at fairly high yields, ranging from 40 to 78%, by conventional and microwave-assisted techniques, and were isolated as a microcrystalline compound. The products obtained in each case were characterized by 1H-NMR, mass spectrometry, elemental analysis, Med-IR and Far-IR. The IR information collected shows good agreement with respect to the density functional theory (DFT) calculations carried out, validating the molecular geometry in each case. This innovative one-pot microwave-based method contributes an efficient pathway for obtaining challenging molecular architectures based on monoporphyrinate complexes without Diglyme.

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来源期刊
Journal of Inclusion Phenomena and Macrocyclic Chemistry
Journal of Inclusion Phenomena and Macrocyclic Chemistry Agricultural and Biological Sciences-Food Science
CiteScore
4.10
自引率
8.70%
发文量
54
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
期刊最新文献
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