太阳能电池的生产及其电学参数的实验表征

Mónica Andrea Botero Londoño, Hermann Raul Vargas Torres, Clara Lilia Calderón Triana
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摘要

在这项工作中,沉积了具有Mo/CuInSe2/CdS/n+–ZnO结构的太阳能电池,并通过I-V曲线进行了实验表征。根据这些结果,对电气参数进行了估计拟合,从理论上确定了曲线中最重要的变量。使用单二极管和双二极管模型进行估计,并比较最适合的曲线。根据用于优化的每个电路模型,估计的变量是光生电流(Iph)、二极管的暗电流(Is)、串联电阻(Rs)、并联电阻(Rp)和二极管理想因子(a1和a2)。用双二极管模型实现的电流-电压(I-V)和功率-电压(P-V)曲线的调整表明,在制造的太阳能电池中,P-n结中存在界面态,这降低了器件的效率。
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PRODUCTION OF SOLAR CELLS AND ESTIMATION OF ITS ELECTRICAL PARAMETERS FROM ITS EXPERIMENTAL CHARACTERIZATION
In this work, solar cells with Mo/CuInSe2/CdS/n+–ZnO structure were deposited and experimentally characterized by the I-V curve. From these results, the electrical parameters were estimated fitting, theoretically, the curve to determine the most important variables. The estimation was carriedout using the single and double diode models and comparing the curve that best fits. The estimated variables were photogenerated current (Iph), dark current of the diode (Is), series resistance (Rs), shunt resistance (Rp) and diode ideality factors (a1 and a2) according to each model of circuit taken for optimization. The adjustment of the current-voltage (I-V) and power-voltage (P-V) curves achieved with the double diodemodel indicates that in the manufactured solar cells, interfacial states are present in the p-n junction, which decreases the efficiency of the device.
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