海滨钛磁铁矿与高炉粉尘共还原焙烧回收钛铁

Q1 Earth and Planetary Sciences International Journal of Mineral Processing Pub Date : 2017-08-10 DOI:10.1016/j.minpro.2017.06.003
Tianyang Hu, Tichang Sun, Jue Kou, Chao Geng, Xiaoping Wang, Chao Chen
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引用次数: 26

摘要

研究了海边钛磁铁矿和高炉粉尘的共还原焙烧,以最大限度地利用这些矿石在印度尼西亚。这种直接还原工艺利用BFD中的固定碳来还原BFD和钛磁铁矿中的铁。用x射线衍射和x射线荧光分析对还原铁粉进行了表征。考察了还原温度、还原时间、C/Fe摩尔比、磨矿细度、萤石用量等还原条件对还原铁粉各项指标的影响。与煤相比,BFD的固定碳和挥发物含量较低。钛和铁的还原和分离对还原焙烧的影响相似。结果表明:焙烧还原的最佳条件为C/Fe摩尔比为0.65,萤石用量为4质量%,焙烧温度为1300℃,焙烧时间为60 min,焙烧产物经两段磨矿和两段磁选得到还原铁粉。前者的铁质量%为94.23,TiO2质量%为0.58,总铁回收率为87.62%。后者含有19.72质量%的Fe和25.47质量%的TiO2,为钛的回收提供了先决条件。
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Recovering titanium and iron by co-reduction roasting of seaside titanomagnetite and blast furnace dust

Co-reduction roasting of seaside titanomagnetite and blast furnace dust was investigated to maximize the use of these ores in Indonesia. This direct reduction process utilizes fixed carbon in BFD to reduce iron from BFD and titanomagnetite. X-ray diffraction and X-ray fluorescence analyses were performed to characterize the reduced iron powder. The influences of reduction conditions, such as reduction temperature and duration, C/Fe molar ratio, grinding fineness and fluorite dose, on the indicators of reduced iron powder were evaluated. Fixed carbon and volatile matter contents were lower in BFD than those in coal. However, reduction and separation of titanium and iron exhibited similar effects on reduction roasting. Results showed that the optimum conditions of roasting reduction included C/Fe molar ratio of 0.65, fluorite dose of 4 mass%, and roasting temperature of 1300 °C for 60 min. The reduced iron powder was obtained through two-stage grinding and two-stage magnetic separation of the roasted product. The former contained 94.23 mass% Fe and 0.58 mass% TiO2 and showed total iron recovery of 87.62%. The latter contained 19.72 mass% Fe and 25.47 mass% TiO2, thereby providing prerequisites for titanium recycling.

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来源期刊
International Journal of Mineral Processing
International Journal of Mineral Processing 工程技术-工程:化工
CiteScore
3.02
自引率
0.00%
发文量
0
审稿时长
11.1 months
期刊介绍: International Journal of Mineral Processing has been discontinued as of the end of 2017, due to the merger with Minerals Engineering. The International Journal of Mineral Processing covers aspects of the processing of mineral resources such as: Metallic and non-metallic ores, coals, and secondary resources. Topics dealt with include: Geometallurgy, comminution, sizing, classification (in air and water), gravity concentration, flotation, electric and magnetic separation, thickening, filtering, drying, and (bio)hydrometallurgy (when applied to low-grade raw materials), control and automation, waste treatment and disposal. In addition to research papers, the journal publishes review articles, technical notes, and letters to the editor..
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