碳化钛负载钌超低负荷高活性碱性析氢电催化剂

IF 2.2 4区 工程技术 Q3 ELECTROCHEMISTRY Journal of electrochemical science and technology Pub Date : 2022-09-14 DOI:10.33961/jecst.2022.00178
Jung-Hyeun Kim, Sang‐Mun Jung, Kyu-Su Kim, Sang-Hoon You, Byung-Jo Lee, Yong‐Tae Kim
{"title":"碳化钛负载钌超低负荷高活性碱性析氢电催化剂","authors":"Jung-Hyeun Kim, Sang‐Mun Jung, Kyu-Su Kim, Sang-Hoon You, Byung-Jo Lee, Yong‐Tae Kim","doi":"10.33961/jecst.2022.00178","DOIUrl":null,"url":null,"abstract":"With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-sup-ported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH 4 in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm -2 . Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.","PeriodicalId":15542,"journal":{"name":"Journal of electrochemical science and technology","volume":" ","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2022-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Highly Active Electrocatalyst based on Ultra-low Loading of Ruthenium Supported on Titanium Carbide for Alkaline Hydrogen Evolution Reaction\",\"authors\":\"Jung-Hyeun Kim, Sang‐Mun Jung, Kyu-Su Kim, Sang-Hoon You, Byung-Jo Lee, Yong‐Tae Kim\",\"doi\":\"10.33961/jecst.2022.00178\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-sup-ported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH 4 in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm -2 . Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.\",\"PeriodicalId\":15542,\"journal\":{\"name\":\"Journal of electrochemical science and technology\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2022-09-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of electrochemical science and technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.33961/jecst.2022.00178\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of electrochemical science and technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.33961/jecst.2022.00178","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 1

摘要

随着水电解催化剂的重要性日益显现,开发高效、廉价的水电解电催化剂在可再生氢能技术中发挥着至关重要的作用。在本研究中,使用电子束蒸发器和在炉中热分解气态CH4,成功地制备了用于析氢反应(HER)的1nm厚度的TiC负载Ru催化剂。所制备的Ru/TiC催化剂在10mAcm-2下的过电位为55mV,在碱性析氢反应中表现出优异的性能。此外,我们证明了Ru/TiC优异的HER性能归因于载体的高表面积和金属-载体的相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Highly Active Electrocatalyst based on Ultra-low Loading of Ruthenium Supported on Titanium Carbide for Alkaline Hydrogen Evolution Reaction
With the emerging importance of catalysts for water electrolysis, developing efficient and inexpensive electrocatalysts for water electrolysis plays a vital role in renewable hydrogen energy technology. In this study, a 1nm thickness of TiC-sup-ported Ru catalyst for hydrogen evolution reaction (HER) has been successfully fabricated using an electron (E)-beam evaporator and thermal decomposition of gaseous CH 4 in a furnace. The prepared Ru/TiC catalyst exhibited an outstanding performance for alkaline hydrogen evolution reaction with an overpotential of 55 mV at 10 mA cm -2 . Furthermore, we demonstrated that the outstanding HER performance of Ru/TiC was attributed to the high surface area of the support and the metal-support interaction.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
6.30
自引率
8.10%
发文量
44
期刊介绍: Covering fields: - Batteries and Energy Storage - Biological Electrochemistry - Corrosion Science and Technology - Electroanalytical Chemistry and Sensor Technology - Electrocatalysis - Electrochemical Capacitors & Supercapcitors - Electrochemical Engineering - Electrodeposition and Surface Treatment - Environmental Science and Technology - Fuel Cells - Material Electrochemistry - Molecular Electrochemistry and Organic Electrochemistry - Physical Electrochemistry - Solar Energy Conversion and Photoelectrochemistry
期刊最新文献
Temperature-Dependent Mn Substitution Effect on LiNiO2 The Effect of Obstacle Number, Shape and Blockage Degree in Flow Field of PEMFC on its Performance Revolutionizing Energy Storage: Exploring Processing Approaches and Electrochemical Performance of Metal-Organic Frameworks (MOFs) and Their Hybrids Electrodeposition of Ni–W/Al<sub>2</sub>O<sub>3</sub> Nano-Composites and the Influence of Al<sub>2</sub>O<sub>3</sub> Incorporation on Mechanical and Corrosion Resistance Behaviours Surface Engineering of GaN Photoelectrode by NH3 Treatment for Solar Water Oxidation
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1