Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza
{"title":"1,2,3-三唑衍生物的合成及其对碳钢缓蚀剂的评价","authors":"Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza","doi":"10.1155/2019/6759478","DOIUrl":null,"url":null,"abstract":"Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":" ","pages":""},"PeriodicalIF":2.3000,"publicationDate":"2019-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2019/6759478","citationCount":"11","resultStr":"{\"title\":\"Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel\",\"authors\":\"Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza\",\"doi\":\"10.1155/2019/6759478\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.\",\"PeriodicalId\":13933,\"journal\":{\"name\":\"International journal of electrochemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2019-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1155/2019/6759478\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International journal of electrochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2019/6759478\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International journal of electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2019/6759478","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel
Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.