1,2,3-三唑衍生物的合成及其对碳钢缓蚀剂的评价

IF 2.3 Q3 ELECTROCHEMISTRY International journal of electrochemistry Pub Date : 2019-01-22 DOI:10.1155/2019/6759478
Gabriel O. Resende, S. Teixeira,, I. F. Figueiredo, Alexandre A. Godoy, Dafne Júlia F. Lougon, B. Cotrim, F. C. Souza
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引用次数: 11

摘要

含有1,2,3-三唑的杂环化合物可以通过点击化学合成,这是一种快速、产率高的反应,只需改变少量试剂,就可以合成多种多样的衍生物。该合成路线使用现成的廉价商业试剂,无需进一步提纯任何产品或中间体,产品收率高。用失重法和电化学法测定了碳钢在酸性介质中的防腐性能。观察到抑制剂1和2的抑制率为90%。从Langmuir等温线推测,缓蚀剂在碳钢表面的吸附可能是通过物理和化学相互作用发生的;然而,活化能的提高表明缓蚀剂在碳钢表面的相互作用是一个物理吸附过程。
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Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel
Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.
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审稿时长
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