水合硅酸镁相的研究进展及前景展望

Q2 Engineering RILEM Technical Letters Pub Date : 2022-09-01 DOI:10.21809/rilemtechlett.2022.162
E. Bernard
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引用次数: 3

摘要

这封简短的信总结了硅酸镁水合物(M-S-H)相的结构和热力学模型的最新研究。M-S-H结构与水合粘土相当,与粘土薄片相比,其微观结构更小、更圆。与粘土矿物类似,M-S-H可以掺入铝等离子和水合可交换阳离子,以补偿表面负电荷。对M-S-H结构的基本理解使我们能够开发基于结构的热力学模型,这可以进一步帮助优化M-S-H的形成及其作为胶结材料的使用条件。含有M-S-H的优化粘合剂具有以下优点:i)良好的机械性能,ii)致密的微观结构和潜在的良好的抗浸出性,以及iii)低pH值。因此,这些类型的粘合剂可用于非钢筋水泥产品、特定废物的封装、含有天然纤维的产品或粘土稳定等。
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Research progress on magnesium silicate hydrate phases and future opportunities
This short letter summaries the latest research on the structure and thermodynamic modelling of the magnesium silicate hydrates (M-S-H) phases. M-S-H structure is comparable to hydrated clays, with a smaller and rounder microstructures compared to clay platelets. Similar to clay minerals, M-S-H can incorporate ions such as aluminium and hydrated exchangeable cations to compensate the negative surface charge. This fundamental understanding of M-S-H structure allowed to develop structure-based thermodynamic models, which can further help to optimise the conditions for M-S-H formation and its use as cementitious materials. Optimized binders containing M-S-H have the advantages of presenting: i) good mechanical properties, ii) dense microstructure and potentially good resistances to leaching and iii) low pH values. These types of binders could therefore be used for cement products with non-steel reinforcement, for the encapsulation of specific wastes, for products containing natural fibres or for the clay stabilisation, etc.
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来源期刊
RILEM Technical Letters
RILEM Technical Letters Materials Science-Materials Science (all)
CiteScore
5.00
自引率
0.00%
发文量
13
审稿时长
10 weeks
期刊最新文献
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