空果束生产琥珀酸的多目标优化

Q4 Chemical Engineering ASEAN Journal of Chemical Engineering Pub Date : 2019-10-24 DOI:10.22146/ajche.50870
R. Hafyan, W. D. Prasetyo, L. Bhullar, Z. Putra, M. Bilad, M. D. H. Wirzal, N. Nordin
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引用次数: 4

摘要

马来西亚种植厂生产的空果包(EFB)造成了一个主要的处理问题。另一方面,可持续性问题促使各行业克服化石燃料的消耗和温室气体排放的减少。因此,作为一种可再生能源,EFB可以通过将其转化为燃料和化学品来解决上述问题,这是一个有吸引力的选择。琥珀酸是DOE确定用于合成高价值材料的12种化学构建块之一,可以通过EFB的生物化学转化生产。本研究从可持续性的三个支柱,即经济、环境和安全的角度,评估了以EFB为原料的琥珀酸生产工艺。应用流程图建模和技术经济分析方法,然后使用遗传算法方法进行多目标优化,同时考虑净现值(NPV)的最大化和全球变暖潜能(GWP)和毒性损害指数(TDI)的最小化。帕累托边界揭示了所有目标之间的权衡,即在71900千克/小时的最大EFB下,最大NPV为1619 MMSD。同时,在50000千克/小时的最低EFB下,获得了最低GWP(12.4千克二氧化碳当量/千克琥珀酸)和TDI(4.5)。
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Multi-objective Optimization of Succinic Acid Production from Empty Fruit Bunch
Empty Fruit Bunch (EFB) produced in plantation mill activities in Malaysia creates a major disposal problem. On the other hand, sustainability issues have driven industries to overcome the depletion of fossil fuels and reduction of greenhouse gases emissions. Therefore, as a renewable source, EFB can be an attractive option to address the above problems by converting it into fuels and chemicals. Succinic acid, one of 12 chemical building blocks identified by DOE to be used in synthesis of high-value materials, can be produced from biochemical conversion of the EFB. The present study evaluates succinic acid production process using EFB as the raw material from the perspective of three pillars of sustainability, namely economic, environment, and safety. Flowsheet modeling and techno-economic analysis methods are applied, followed by a multi-objective optimization using genetic algorithm method that simultaneously accounts for maximization of Net Present Value (NPV) and minimization of both Global Warming Potential (GWP) and Toxicity Damage Index (TDI). The pareto frontier reveals a trade-off among all objectives that the maximum NPV is 1,619 MMSD at the maximum EFB of 71,900 kg/hour. Meanwhile, the minimum GWP (12.4 kg CO2-eq/kg succinic acid) and TDI (4.5) are acquired at the minimum EFB of 50,000 kg/hour.
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来源期刊
ASEAN Journal of Chemical Engineering
ASEAN Journal of Chemical Engineering Chemical Engineering-Chemical Engineering (all)
CiteScore
1.00
自引率
0.00%
发文量
15
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