V. N. Kokozay, E. V. Polunkin, O. Yu. Vassilyeva, T. M. Kameneva, V. S. Pilyavskiy, B. W. Skelton
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Homo- and Heteronuclear Cobalt(III)-Based Complexes with 2-Methoxy-6-[(Methylimino)Methyl]Phenol: Structure and Antioxidant Properties
CoL3·DMF, [CoCdCl2L3]·0.5H2O, and [CoMnCl2L3]·H2O complexes, where HL is a product of the condensation of o-vanillin and methylamine have been obtained. The crystal structure of the latter complex has been determined by X-ray structural analysis. The study of the antioxidant activity of these complexes in a model reaction of radical-chain oxidation of benzyl alcohol with an atmospheric oxygen has proved a significant inhibition of this process at concentrations of the complexes of 10–7-10–6 mol/L. It is established that the inhibitory activity of the compounds depends on the nature of the metal ions present in the complex.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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