{"title":"4,4'-联吡啶与苯醌衍生物电荷转移配合物的卷积-反卷积伏安法","authors":"A. Al-Owais, I. El-Hallag, E. El-Mossalamy","doi":"10.14447/jnmes.v24i3.a07","DOIUrl":null,"url":null,"abstract":"Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.","PeriodicalId":16447,"journal":{"name":"Journal of New Materials For Electrochemical Systems","volume":" ","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Convolutive Deconvolutive Voltammetry of Charge Transfer Complexes of 4,4’-Bipyridine With Benzoquinone Derivatives\",\"authors\":\"A. Al-Owais, I. El-Hallag, E. El-Mossalamy\",\"doi\":\"10.14447/jnmes.v24i3.a07\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.\",\"PeriodicalId\":16447,\"journal\":{\"name\":\"Journal of New Materials For Electrochemical Systems\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2021-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of New Materials For Electrochemical Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.14447/jnmes.v24i3.a07\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of New Materials For Electrochemical Systems","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.14447/jnmes.v24i3.a07","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Convolutive Deconvolutive Voltammetry of Charge Transfer Complexes of 4,4’-Bipyridine With Benzoquinone Derivatives
Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.
期刊介绍:
This international Journal is intended for the publication of original work, both analytical and experimental, and of reviews and commercial aspects related to the field of New Materials for Electrochemical Systems. The emphasis will be on research both of a fundamental and an applied nature in various aspects of the development of new materials in electrochemical systems.