4,4'-联吡啶与苯醌衍生物电荷转移配合物的卷积-反卷积伏安法

IF 0.7 4区 材料科学 Q4 ELECTROCHEMISTRY Journal of New Materials For Electrochemical Systems Pub Date : 2021-09-30 DOI:10.14447/jnmes.v24i3.a07
A. Al-Owais, I. El-Hallag, E. El-Mossalamy
{"title":"4,4'-联吡啶与苯醌衍生物电荷转移配合物的卷积-反卷积伏安法","authors":"A. Al-Owais, I. El-Hallag, E. El-Mossalamy","doi":"10.14447/jnmes.v24i3.a07","DOIUrl":null,"url":null,"abstract":"Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.","PeriodicalId":16447,"journal":{"name":"Journal of New Materials For Electrochemical Systems","volume":" ","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2021-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Convolutive Deconvolutive Voltammetry of Charge Transfer Complexes of 4,4’-Bipyridine With Benzoquinone Derivatives\",\"authors\":\"A. Al-Owais, I. El-Hallag, E. El-Mossalamy\",\"doi\":\"10.14447/jnmes.v24i3.a07\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.\",\"PeriodicalId\":16447,\"journal\":{\"name\":\"Journal of New Materials For Electrochemical Systems\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2021-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of New Materials For Electrochemical Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.14447/jnmes.v24i3.a07\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of New Materials For Electrochemical Systems","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.14447/jnmes.v24i3.a07","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

采用卷积、去卷积循环伏安法、数字模拟、计时电流法、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对4,4’-联吡啶与苯醌衍生物的电荷转移络合物(CT)进行了表征。这些研究是在TBAPL/CH2Cl2中的金电极上完成的。通过上述方法计算和解释了所研究的CT复合物的电极反应类型和动力学参数,然后通过数字模拟进行了确认。进行SEM和TEM以表征所提出的配合物的结构形态以及显示配合物的纳米结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Convolutive Deconvolutive Voltammetry of Charge Transfer Complexes of 4,4’-Bipyridine With Benzoquinone Derivatives
Convolutive, deconvolutive cyclic voltammetric, digital simulation, chrono- amperometric, scanning electron microscopy (SEM) and transmission electron micro- scopy (TEM) were used for clarifying the characterization of charge transfer complex (CT) of 4,4’-bipyridine with benzoquinone derivatives. These studies were achieved at a gold electrode in TBAPL/CH2Cl2. The kind of the electrode reaction and the kinetic parameters of the CT complex under study were calculated and explained via the above methods, then confirmed via digital simulation. SEM and TEM were performed for characterization of the structural morphology of the presented complex as well as showing the nanostructured of the complex.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of New Materials For Electrochemical Systems
Journal of New Materials For Electrochemical Systems ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
1.90
自引率
0.00%
发文量
33
审稿时长
>12 weeks
期刊介绍: This international Journal is intended for the publication of original work, both analytical and experimental, and of reviews and commercial aspects related to the field of New Materials for Electrochemical Systems. The emphasis will be on research both of a fundamental and an applied nature in various aspects of the development of new materials in electrochemical systems.
期刊最新文献
Effect of Ceramic Coated Tool on Stray Cut in Electrochemical Micromachining Hybrid Optimization Algorithms for Maximum Power Point Tracking based Incremental Conductance Techniques with Solar Cell Synthesis of Graphene Oxide Coating on ZnCo2S4 Using Hydrothermal Method for Electrochemical Capacitors Applications Harmonics Reduction and Balanced Transition in Hybrid Renewable Energy Sources in a Micro Grid Power System Tuning the Particle Size Distribution at Cathode for Enhanced Li-Ion Battery Performance
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1