手性酰胺键合羟基喹啉取代卟啉荧光探针的“off-on-off”pH传感特性

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2022-11-08 DOI:10.1007/s10847-022-01168-9

Syed Najeeb-Uz-Zaman Haider, Tingting Gu, Rongping Tang, Weihua Zhu, Xu Liang

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摘要

本文制备了一系列四种酰胺键羟基喹啉取代卟啉并对其进行了表征。通过光谱和电化学分析研究了电子结构的变化趋势，以探讨功能化酰胺键合羟基喹啉单元的影响。同时，研究了其选择性pH敏感性能，并提出了其可能的机理。提出的机理是光致电子转移机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Chiral amide-bonded hydroxyquinoline-substituted porphyrin fluorescent probes “off–on–off” pH sensing properties

Herein, a series of four amide-bonded hydroxyquinoline-substituted porphyrins have been prepared and characterized. Trends in the electronic structures are investigated by spectroscopic and electrochemical analysis to explore the effect of the functional amide-bonded hydroxyquinoline units. Also, the selective pH sensing properties were also performed and their plausible mechanism were also proposed. And the proposed mechanisms is the photoinduced electron transfer mechanism.

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来源期刊

Journal of Inclusion Phenomena and Macrocyclic Chemistry Agricultural and Biological Sciences-Food Science

CiteScore

4.10

自引率

8.70%

发文量

期刊介绍： The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.