Chunhui Mou, Hui Li, Ning Dong, S. Hui, Denghui Wang
{"title":"Ce对MnOx/Al2O3上NO吸附和氧化的影响","authors":"Chunhui Mou, Hui Li, Ning Dong, S. Hui, Denghui Wang","doi":"10.1155/2021/3131309","DOIUrl":null,"url":null,"abstract":"The MnO\n \n \n \n \n x\n \n \n \n /Al2O3 catalysts with different Ce content doping were prepared by an ultrasonic impregnation method, and the catalytic activity for NO oxidation removal was tested in a fixed-bed quartz tube furnace. Simultaneously, the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), full-automatic physical-chemical adsorption instrument, and field emission scanning electron microscope (FESEM) to analyze the effect of Ce addition on the adsorption capacity and catalytic activity. Experimental results validated that the activity of the MnO\n \n \n \n \n x\n \n \n \n /Al2O3 catalyst was greatly promoted with Ce addition. According to the characterization results, it could be concluded that Ce doping led to significant changes in the crystalline phase on the catalyst surface, which increased the relative content of surface lattice oxygen and promoted the catalytic oxidation of NO. By observing the physical properties of the surface and analyzing the surface elements of the catalyst, it could be inferred that a manganese-cerium solid solution was formed on the surface of Mn0.4Ce0.05/Al. Moreover, Ce addition increased the catalyst pore size, which enhanced the adsorption and contact of NO and O2 with the active sites on the catalyst surface, and reduced the resistance of the reactants during internal diffusion. All these variations assigned to Mn0.4Ce0.05/Al were favorable for the catalytic oxidation of NO.","PeriodicalId":7315,"journal":{"name":"Adsorption Science & Technology","volume":" ","pages":""},"PeriodicalIF":2.8000,"publicationDate":"2021-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Effect of Ce Addition on Adsorption and Oxidation of NO over MnO\\n \\n \\n \\n x\\n \\n \\n /Al2O3\",\"authors\":\"Chunhui Mou, Hui Li, Ning Dong, S. Hui, Denghui Wang\",\"doi\":\"10.1155/2021/3131309\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The MnO\\n \\n \\n \\n \\n x\\n \\n \\n \\n /Al2O3 catalysts with different Ce content doping were prepared by an ultrasonic impregnation method, and the catalytic activity for NO oxidation removal was tested in a fixed-bed quartz tube furnace. Simultaneously, the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), full-automatic physical-chemical adsorption instrument, and field emission scanning electron microscope (FESEM) to analyze the effect of Ce addition on the adsorption capacity and catalytic activity. Experimental results validated that the activity of the MnO\\n \\n \\n \\n \\n x\\n \\n \\n \\n /Al2O3 catalyst was greatly promoted with Ce addition. According to the characterization results, it could be concluded that Ce doping led to significant changes in the crystalline phase on the catalyst surface, which increased the relative content of surface lattice oxygen and promoted the catalytic oxidation of NO. By observing the physical properties of the surface and analyzing the surface elements of the catalyst, it could be inferred that a manganese-cerium solid solution was formed on the surface of Mn0.4Ce0.05/Al. Moreover, Ce addition increased the catalyst pore size, which enhanced the adsorption and contact of NO and O2 with the active sites on the catalyst surface, and reduced the resistance of the reactants during internal diffusion. All these variations assigned to Mn0.4Ce0.05/Al were favorable for the catalytic oxidation of NO.\",\"PeriodicalId\":7315,\"journal\":{\"name\":\"Adsorption Science & Technology\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2021-09-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Adsorption Science & Technology\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1155/2021/3131309\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Adsorption Science & Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1155/2021/3131309","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Effect of Ce Addition on Adsorption and Oxidation of NO over MnO
x
/Al2O3
The MnO
x
/Al2O3 catalysts with different Ce content doping were prepared by an ultrasonic impregnation method, and the catalytic activity for NO oxidation removal was tested in a fixed-bed quartz tube furnace. Simultaneously, the catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), full-automatic physical-chemical adsorption instrument, and field emission scanning electron microscope (FESEM) to analyze the effect of Ce addition on the adsorption capacity and catalytic activity. Experimental results validated that the activity of the MnO
x
/Al2O3 catalyst was greatly promoted with Ce addition. According to the characterization results, it could be concluded that Ce doping led to significant changes in the crystalline phase on the catalyst surface, which increased the relative content of surface lattice oxygen and promoted the catalytic oxidation of NO. By observing the physical properties of the surface and analyzing the surface elements of the catalyst, it could be inferred that a manganese-cerium solid solution was formed on the surface of Mn0.4Ce0.05/Al. Moreover, Ce addition increased the catalyst pore size, which enhanced the adsorption and contact of NO and O2 with the active sites on the catalyst surface, and reduced the resistance of the reactants during internal diffusion. All these variations assigned to Mn0.4Ce0.05/Al were favorable for the catalytic oxidation of NO.
期刊介绍:
Adsorption Science & Technology is a peer-reviewed, open access journal devoted to studies of adsorption and desorption phenomena, which publishes original research papers and critical review articles, with occasional special issues relating to particular topics and symposia.