放电等离子体对饮用水的消毒

D. Charny, D. Yaroshchuk, O. Puhach, G. Smirnova, O. Musich, M. Stokolos, V. Nikolenko, I. Tishchenko, N. Chernova
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引用次数: 1

摘要

今天,考虑到使用含氯化合物的消毒技术效率低,以及抗氯微生物数量不断增加,在供水和排水领域引入替代消毒方法的问题是相关的。一种这样的替代方法是用放电等离子体处理液体。本文介绍了我们对基辅地表水源不同类型的水和故意感染大肠杆菌的水的处理实验。实验在实验室装置上进行,该装置具有循环泵和具有集成电极的喷射器型反应器。在反应器中形成水-空气混合物,其中发生放电。消毒反应器和同时形成非均质水-空气环境的装置是一个喷射器,其中插入电极,接收电流脉冲。放电引发一系列不同的物理化学现象,如强电场、强紫外线辐射、过压冲击波,特别是形成各种高活性化学物质,如自由基(OH•、H•、O•)和分子(H2O2、H2、O2、O3)。所有这些物理化学过程都发生在放电过程中,例如,短寿命自由基的形成和作用,以及相对长寿命的氧化剂的作用。通过将两个试管中的冲洗液引入反应槽,研究了微生物浓度对工业(自来水)中水消毒速率和完全性的影响。这提供了3.4∙106 CFU/cm3的大肠杆菌初始浓度。30秒的水处理使微生物浓度降低了两个数量级(高达5.4∙104)。处理1分钟后,这一数字降至1.7∙102,3分钟后降至5.2 CFU/cm3,即处理后的水几乎符合纯水的标准。实验已经证明了血浆消毒的有效性,即使对于微生物浓度显著超过最大允许浓度的液体也是如此。处理前后的微生物含量通过限制稀释样品的方法测定,随后在培养皿中的营养培养基上播种
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DISINFECTION OF DRINKING WATER BY ELECTRIC DISCHARGE PLASMA
For today, taking into account the low efficiency of the disinfection technologies using chlorine-containing compounds and the growing number of chlorine-resistant microorganisms, the question of introducing alternative methods of disinfection in the field of water supply and drainage is relevant. One such alternative method is the treatment of liquids with plasma of electric discharge. This article describes our experiments on the treatment of different types of water from surface sources in Kyiv and water intentionally infected with Escherichia coli (E. coli). The experiments were performed on a laboratory installation with a circulating pump and an ejector-type reactor with integrated electrodes. In the reactor a water-air mixture is formed, in which an electric discharge takes place. The disinfection reactor and at the same time the device for the formation of a heterogeneous water-air environment is an ejector with electrodes inserted into it, which receive pulses of electric current. Discharges initiate a range of different physicochemical phenomena, such as a strong electric field, intense ultraviolet radiation, shock waves of excess pressure and, in particular, the formation of various highly active chemicals such as radicals (OH •, H •, O •) and molecules ( H2O2, H2, O2, O3). All these physicochemical processes occur during the discharge itself, for example, the formation and action of short-lived radicals, as well as the action of relatively long-lived oxidants. The effect of the concentration of microorganisms on the rate and completeness of water disinfection was studied in technical (tap) water with the introduction into the reaction tank of the washoff from two test tubes. This provided an initial concentration of E. coli of 3.4 ∙ 106 CFU / cm3. Water treatment for 30 seconds reduced the concentration of microorganisms by two orders of magnitude (up to 5.4 ∙ 104). After 1 minute of treatment, this figure decreased to 1.7 ∙ 102, and after 3 minutes to 5.2 CFU / cm3, i.e., the treated water corresponded to norms for almost pure water. Experiments have proven the effectiveness of plasma disinfection, even for liquids with a concentration of microorganisms significantly exceeding the maximum allowable concentrations. The content of microorganisms before and after treatment was determined by the method of limiting dilution of samples with subsequent sowing on a nutrient medium in Petri dishes
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