低压易泄漏气井凝胶塞暂堵压井技术研究

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2020-10-01 DOI:10.2118/204213-pa
Xiong Ying, Xu Yuan, Zhang Yadong, F. Ziyi
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引用次数: 7

摘要

针对低压井普遍存在的压井液泄漏问题,提出了一种适用于临时封堵技术的凝胶塞系统;现有用于压井临时封堵的凝胶塞技术强度低;交联时间难以控制;以及凝胶脆化和破坏某些凝胶塞的困难。将醚化的半乳甘露聚糖植物胶、异辛醇聚氧乙烯醚表面活性剂和油相的混合物用作增稠剂。使用含有长链多羟基醇的无机盐络合物作为交联剂,并且长链多羟醇的浓度远远超过络合金属离子所需的理论量。使用多羟基醇与少量弱酸的混合物作为交联调节剂。最后,使用硫代硫酸钠和长链季铵盐表面活性剂的混合物作为稳定剂。实验室评估表明,这种凝胶塞系统在混合均匀后可以直接泵入井筒,并且该系统在表面上的粘度可以通过交联调节剂的量来控制。凝胶化后的凝胶塞系统的粘度高(粘弹性固体胶体);在120°C时,初始粘度达到30000 mPa·s,老化72小时后仍保持半固体凝胶状 小时。当凝胶加热到目标区域温度时,出现直角增厚。酸性液体破胶剂作用迅速,破胶液1~4天后粘度低于5mPa·s 小时。该暂堵压井胶塞技术已成功应用于低压易漏气井。压井后,裸井中没有气体、压力或液体残留,井口成功更换,油管成功拆除。凝胶塞还表现出自修复性:环空中的凝胶塞可以自动填充和密封油管形成的孔。胶塞中73 mm油管的静摩擦(外壁)为39.6 t/km;油管拆除后的动摩擦(外壁)为7.2t/km。因此,这种凝胶塞有望成为低压、易泄漏气井修井作业中的一种临时封堵技术。
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Study of Gel Plug for Temporary Blocking and Well-Killing Technology in Low-Pressure, Leakage-Prone Gas Well
A gel-plug system for temporary blocking technology is proposed in this paper to address the prevalent leakage of killing fluid in low-pressure wells; the low technical strength of existing gel plugs for temporary blocking in well killing; difficult-to-control crosslinking time; and gel embrittlement and the difficulty of breaking certain gel plugs. A mixture of etherified galactomannan plant gum, isooctanol polyoxyethylene ether surfactant, and oil phase was used as a thickener. An inorganic salt complex containing long-chain polyhydroxy alcohol was used as a crosslinker and the concentration of long-chain polyhydroxy alcohol far exceeds the theoretical amount required to complex the metal ion. A mixture of polyhydroxy alcohol with a small amount of weak acid was used as a crosslinking regulator. Finally, a mixture of sodium thiosulfate and long-chain quaternary ammonium salt surfactant was used as a stabilizer. Laboratory evaluations showed that this gel-plug system can be directly pumped into the wellbore after being mixed homogeneously, and the viscosity of the system on the surface can be controlled by the amount of crosslinking regulator. The viscosity of the gel-plug system after gelling was high (viscoelastic solid colloid); the initial viscosity reached 30 000 mPa·s at 120°C and retained a semisolid gel shape after aging for 72 hours. Right-angle thickening occurred when the gel warmed to target-zone temperature. The acidic liquid breaker acted quickly, and the viscosity of the broken fluid was lower than 5 mPa·s after 1 to 4  hours. This gel plug for temporary blocking and well-killing technology was successfully applied in a low-pressure, leakage-prone gas well. No gas, pressure, or liquid remained in the open well after killing, the wellhead was successfully replaced, and the tubing was successfully removed. The gel plug also exhibited self-healing: The hole formed by the tubing could be filled and sealed automatically by the gel plug in the annulus. The static friction (outer wall) of 73-mm tubing in the gel plug was 39.6 t/km; the dynamic friction (outer wall) after tubing removal was 7.2 t/km. This gel plug thus shows promise as a temporary blocking technology in workover operations of low-pressure, leakage-prone gas wells.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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