新型铅配位聚合物[Pb(L)(1,3-bdc)]·2H2O的合成与结构表征

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Main Group Metal Chemistry Pub Date : 2022-01-01 DOI:10.1515/mgmc-2022-0021

Zirui Li, Jiaqi Zhao, M. Lou, Xiuyan Wang

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引用次数: 2

摘要

摘要在水热条件下成功制备了新型配位聚合物[Pb(L)(1,3-bdc)]·2H2O (1)， (L = 2-(2,6-二氯苯基)- 1h -咪唑[4,5-f][1,10]菲罗啉，1,3- h2bdc = 1,3-苯二羧酸)。1的结构是一维链结构，通过π -π相互作用和C-H⋯π相互作用进一步堆叠在一起形成三维超分子结构。此外，还对1的热重分析进行了研究。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis and structural characterization of a novel lead coordination polymer: [Pb(L)(1,3-bdc)]·2H2O

Abstract A novel coordination polymer, [Pb(L)(1,3-bdc)]·2H2O (1), (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 1,3-H2bdc = 1,3-benzenedicarboxylic acid) has been successfully prepared under hydrothermal conditions. The structure of 1 is a 1D chain structure, which further stacks together to form a 3D supramolecular architecture by π–π interactions and C–H⋯π interactions. In addition, the thermogravimetric analysis of 1 has been investigated.

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.