具有高维模型项的小混合过程变量实验的设计、构造和模型选择

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2022-12-15 DOI:10.1080/08982112.2022.2135444
K. Chatterjee, Chang-Yun Lin
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引用次数: 0

摘要

摘要本文考虑了变量数量较大的混合工艺变量实验的设计构造和模型选择问题。对于这样的实验,不能得到广义最小二乘估计,因此很难识别重要的模型项。为了克服这些问题,本文采用广义贝叶斯- d准则选择最优设计,并应用贝叶斯分析方法选择最优模型。开发了两种算法来实现所提出的方法。一个鱼饼实验演示了贝叶斯方法如何应用于实际实验。仿真研究表明,该方法具有较强的重要项识别能力和较好的ⅰ类误差控制能力。
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Design construction and model selection for small mixture-process variable experiments with high-dimensional model terms
Abstract This paper considers the design construction and model selection for mixture-process variable experiments where the number of variables is large. For such experiments the generalized least squares estimates cannot be obtained and hence it will be difficult to identify the important model terms. To overcome these problems, here we employ the generalized Bayesian-D criterion to choose the optimal design and apply the Bayesian analysis method to select the best model. Two algorithms are developed to implement the proposed methods. A fish-patty experiment demonstrates how the Bayesian approach can be applied to a real experiment. Simulation studies show that the proposed method has a high power to identify important terms and well controls the type I error.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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