C. Puzzarini, S. Alessandrini, L. Bizzocchi, M. Melosso, V. Rivilla
{"title":"从实验室到星际介质:在太空中寻找外来分子的策略","authors":"C. Puzzarini, S. Alessandrini, L. Bizzocchi, M. Melosso, V. Rivilla","doi":"10.3389/fspas.2023.1211784","DOIUrl":null,"url":null,"abstract":"The chemistry of the interstellar medium occurs under extreme conditions and can lead to the formation of exotic molecules. These are species that on Earth are unstable and/or highly reactive. Their discovery in space is usually based on the astronomical observation of their rotational fingerprints, which requires an accurate laboratory investigation. This is based on a strategy that starts from the interplay of experiment and theory. State-of-the-art quantum-chemical calculations are used to predict the relevant spectroscopic information required to guide the spectral recording, analysis and assignment. Rotational spectra measurements are then performed in the centimeter-/millimeter-/submillimeter-wave region, thereby exploiting efficient on-the-fly production protocols for exotic molecules. Subsequently, the spectral analysis leads to accurate spectroscopic parameters, which are then used for setting up accurate line catalogs for astronomical searches and detections. This review is based on the strategy developed and the results obtained at the ROT&Comp Lab of the University of Bologna.","PeriodicalId":46793,"journal":{"name":"Frontiers in Astronomy and Space Sciences","volume":" ","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2023-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"From the laboratory to the interstellar medium: a strategy to search for exotic molecules in space\",\"authors\":\"C. Puzzarini, S. Alessandrini, L. Bizzocchi, M. Melosso, V. Rivilla\",\"doi\":\"10.3389/fspas.2023.1211784\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The chemistry of the interstellar medium occurs under extreme conditions and can lead to the formation of exotic molecules. These are species that on Earth are unstable and/or highly reactive. Their discovery in space is usually based on the astronomical observation of their rotational fingerprints, which requires an accurate laboratory investigation. This is based on a strategy that starts from the interplay of experiment and theory. State-of-the-art quantum-chemical calculations are used to predict the relevant spectroscopic information required to guide the spectral recording, analysis and assignment. Rotational spectra measurements are then performed in the centimeter-/millimeter-/submillimeter-wave region, thereby exploiting efficient on-the-fly production protocols for exotic molecules. Subsequently, the spectral analysis leads to accurate spectroscopic parameters, which are then used for setting up accurate line catalogs for astronomical searches and detections. This review is based on the strategy developed and the results obtained at the ROT&Comp Lab of the University of Bologna.\",\"PeriodicalId\":46793,\"journal\":{\"name\":\"Frontiers in Astronomy and Space Sciences\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2023-08-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers in Astronomy and Space Sciences\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.3389/fspas.2023.1211784\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ASTRONOMY & ASTROPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers in Astronomy and Space Sciences","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.3389/fspas.2023.1211784","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ASTRONOMY & ASTROPHYSICS","Score":null,"Total":0}
From the laboratory to the interstellar medium: a strategy to search for exotic molecules in space
The chemistry of the interstellar medium occurs under extreme conditions and can lead to the formation of exotic molecules. These are species that on Earth are unstable and/or highly reactive. Their discovery in space is usually based on the astronomical observation of their rotational fingerprints, which requires an accurate laboratory investigation. This is based on a strategy that starts from the interplay of experiment and theory. State-of-the-art quantum-chemical calculations are used to predict the relevant spectroscopic information required to guide the spectral recording, analysis and assignment. Rotational spectra measurements are then performed in the centimeter-/millimeter-/submillimeter-wave region, thereby exploiting efficient on-the-fly production protocols for exotic molecules. Subsequently, the spectral analysis leads to accurate spectroscopic parameters, which are then used for setting up accurate line catalogs for astronomical searches and detections. This review is based on the strategy developed and the results obtained at the ROT&Comp Lab of the University of Bologna.