高效液相色谱法测定杀虫剂高效氯氰菊酯热处理后的残留

Laith Al-Ramadany, N. al-Mallah
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引用次数: 0

摘要

本研究旨在评价在实验室条件下,使用30、40和50℃3种温度和6、12、24、48和96小时/度5个暴露时间对水中氯氟氰菊酯残留的影响,并采用高效液相色谱法测定这些残留,并对这些残留进行热处理前后的生物学评价。该农药残留的HPLC测定结果表明,在30 ppm /活性物质浓度、30℃、暴露时间为48 h时,总平均降解率最高(93.47%),平均降解率为94.79%。在10 ppm浓度和40℃温度下,24和48 h的杀虫剂处理效果下降率最高,分别为99.22%和98.33%。这可能表明该农药对所使用温度的敏感性明显高于其初始极限,而在48小时内降解率最高,为89.80%,与其他平均水平有显著差异,暴露6、12、24和96小时分别为82.2、85.26、89.35和8.6.95%。
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Determination of the Residues of the Insecticide Lambda-cyhalothrin After Heat Treatment Using HPLC and Biological Evaluation
The present study was conducted with the aim of evaluating the effect of using three temperatures of 30, 40, and 50 °C and five exposure periods of 6, 12, 24, 48 and 96 hours/degree in reducing Lambda-cyhalothrin residues in water under laboratory conditions and measuring these residues using HPLC as well as Biological evaluation of these residues before and after thermal treatments. The HPLC readings of the residues of this pesticide showed that the highest general average of the degradation rate was at a concentration of 30 ppm /active substance (93.47%) and at a temperature of 30 °C (94.79) and for an exposure period of 48 hours (89.80%). and that the percentage of deterioration in the effectiveness of the pesticide against adults of the insect T.confusum ranged between 96.72 and 99.22%, and the highest of these percentages was at a concentration of 10 ppm (99.22%) and at a temperature of 40 ° C (98.33%) and for the two exposure periods 24 and 48 hours (98.29%). This may indicate the sensitivity of this pesticide to the temperatures used, which was apparently high in its initial limit, while the highest rate of degradation was 89.80% at the 48-hour period, which differed significantly from the rest of the other averages, which amounted to 82.2 , 85.26, 89.35 and 8 6.95% for exposure periods of 6, 12, 24 and 96 hours, respectively.
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审稿时长
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