二氧化碳表面变化:是否来自平流层?

M. Prather
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引用次数: 1

摘要

摘要大气中二氧化碳的波动可以非常精确地测量,并用于确定人为驱动的来源以及海洋和陆地碳的自然循环。可变性的一个来源是平流层,在那里,老化的二氧化碳耗尽的空气流入会在地表产生波动。据推测,这一过程是CO2年际变率(IAV)的一个潜在来源,可能会模糊其他年际变率来源的量化。鉴于最近成功地证明了平流层流入的N2O和含氯氟烃的空气是南半球地表IAV的主要来源,我在这里对CO2应用了相同的模型和测量分析。使用化学输运模型或对观测到的N2O变率进行缩放,我发现平流层驱动的CO2表面变率最多占观测到的IAV的10%,并不是一个重要的来源。通过年方差诊断1985 - 2021年CO2年周期的振幅及其增加,得出的速率与北半球(BRW, MLO)的传统方法相似,但可以识别南半球(SMO, CGO)出现的小趋势(0.08 ppm / 10年)。
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CO2 surface variability: from the stratosphere or not?
Abstract. Fluctuations in atmospheric CO2 can be measured with great precision and are used to identify human-driven sources as well as natural cycles of ocean and land carbon. One source of variability is the stratosphere, where the influx of aged CO2-depleted air can produce fluctuations at the surface. This process has been speculated to be a potential source of interannual variability (IAV) in CO2 that might obscure the quantification of other sources of IAV. Given the recent success in demonstrating that the stratospheric influx of N2O- and chlorofluorocarbon-depleted air is a dominant source of their surface IAV in the Southern Hemisphere, I apply the same model and measurement analysis here to CO2. Using chemistry-transport modeling or scaling of the observed N2O variability, I find that the stratosphere-driven surface variability in CO2 is at most 10 % of the observed IAV and is not an important source. Diagnosing the amplitude of the CO2 annual cycle and its increase from 1985 to 2021 through the annual variance gives rates similar to traditional methods in the Northern Hemisphere (BRW, MLO) but can identify the emergence of small trends (0.08 ppm per decade) in the Southern Hemisphere (SMO, CGO).
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