Daniel Duvinage, Artem Schröder, E. Lork, J. Beckmann
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引用次数: 0
摘要
[Li(1,2- f2c6h4)] [B(C6F5)4](1)和Cs[B(C6F5)4](2)的晶体结构分别由6个Li···F触点(1.965(3)−2.312(3)Å)和12个Cs···F触点(3.0312(1)−3.7397(2)Å)组成，明显短于van der Waals半径之和(3.29和4.90 Å)。
New crystal structures of alkali metal tetrakis(pentafluorophenyl)borates
Abstract The crystal structures of the salts [Li(1,2-F2C6H4)] [B(C6F5)4] (1) and Cs[B(C6F5)4] (2) comprise six Li···F contacts (1.965(3) − 2.312(3) Å) and twelve Cs···F contacts (3.0312(1) − 3.7397(2) Å), respectively, which are significantly shorter than the sum of van der Waals radii (3.29 and 4.90 Å).
期刊介绍：
This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.
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