固相中微量金属元素的保留因子及适用的吸附模型——以辣木为例

M. D. Yéhé, E. Odoh, P. Atheba, Joel Cyriaque Dadje, G. Gbassi
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引用次数: 0

摘要

辣木是一种可食用植物,在整个热带地区都有种植。它属于辣木科,是已知的14种之一。本文对天然吸附剂辣木籽粉吸附微量金属元素的主要因素进行了综合研究。研究了金属浓度、溶液pH、吸附剂粒径、吸附剂剂量和吸附剂/吸附剂接触时间五个主要因素。通过这些因素,我们提出了去除这些TMEs的最佳条件,以及适用于吸附剂保留这些金属阳离子条件的吸附等温线模型。20 min (GD)和50 min (GND)的时间是我们研究中得到的平衡时间。最佳吸附剂质量(GD和GND粉)为4.5 g。平均pH值在6至8之间时,可观察到20%至97%的减少。在20°C、30°C、40°C和50°C等温线实验中得到的决定系数(R2)(0.972、0.963、0.991和0.799)接近于1。Langmuir等温线的基本特征分离因子RL的取值范围在0 ~ 1之间,证明了Langmuir等温线模型对辣木粉吸附铜的实验数据的适用性。在本文中,我们对以下TMEs (Mn, Ni, Cr, Cu, Cd, Co, Pb, Fe, Zn, Ag)特别感兴趣。
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Retention Factors for Trace Metal Elements in Solid Phase and Applicable Adsorption Models: Case of Moringa oleifera
Moringa oleifera is an edible plant cultivated throughout the tropical belt. It belongs to the family Moringaceae and is one of its 14 known species. This paper presents a synthesis of the main factors responsible for the retention of trace metal elements (TMEs) by Moringa oleifera seed powder, a natural adsorbent. The five main factors studied are metal concentration, solution pH, adsorbent particle size, adsorbent dose and adsorbent/adsorbate contact time. Through these factors, we present the optimal conditions for removal of these TMEs, as well as adsorption isotherm models appropriate for the conditions of retention of these metal cations by the adsorbent. The times of 20 min (GD) and 50 min (GND) are the equilibrium times obtained in our study. An optimal adsorbent mass (GD and GND powders) of 4.5 g was found. 20% to 97% abatement is observed for average pH values between 6 and 8. The coefficients of determination (R2) obtained (0.972, 0.963, 0.991 and 0.799) during the isotherm experiments carried out at 20°C, 30°C, 40°C and 50°C are close to 1. Also, the separation factor (RL), an essential characteristic of the Langmuir isotherm whose values are between 0 and 1, attest to the applicability of the Langmuir isotherm model to fit the experimental data of copper adsorption by Moringa powders. In this paper, we are particularly interested in the following TMEs (Mn, Ni, Cr, Cu, Cd, Co, Pb, Fe, Zn, Ag).
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