x射线和伽马辐射下石墨烯退火cu掺杂Li2B4O7+PTFE的热致发光研究

IF 2.4 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Molecular and Engineering Materials Pub Date : 2020-11-28 DOI:10.1142/s2251237320500057
S. Thiyagarajan, M. Vallejo, P. Ceron, C. Gómez-Solis, C. Wiechers, E. Montes, R. Navarro, M. Sosa
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引用次数: 1

摘要

用0.1%的铜掺杂四硼酸锂(LTB)以增强LTB的热致发光性能。石墨烯还原气氛用于增加晶体结构中的氧空位。LTB:Cu[公式:见正文]通过将Li2B4O7:Cu与PTFE以4:1的比例混合来制备PTFE(聚四氟乙烯)颗粒。通过X射线衍射(XRD)和扫描电子显微镜(SEM)对所得材料进行了表征。获得平均尺寸为134[式:见正文]nm的Li2B4O7晶体。SEM证实了铜的存在。使用[公式:见正文]钴源,用[公式:见图正文]辐射研究了LTB:Cu-PTFE颗粒的TL响应。TTL响应显示出依赖于辐射剂量的线性行为。通过用X射线照射,从2[公式:见正文]h到10[公式:参见正文]h分析退火时间对TL辉光曲线的影响。研究了质量对TL响应的影响,将样品的质量从10[公式:见正文]mg变为50[公式:参见正文]mg。从各种加热速率的研究中可以观察到,当加热速率逐渐增加时,TL强度增加。利用计算机反褶积方法计算了动力学参数。剂量特性结果表明,该材料在医疗领域的放射治疗用辐射剂量计中具有良好的应用潜力。
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Thermoluminescence of Cu-Doped Li2B4O7+PTFE Annealed by Graphene Exposed to X-Rays and Gamma Radiation
Lithium tetraborate (LTB) was doped with copper (0.1%) to enhance the LTB thermoluminescent (TL) properties. A graphene reducing atmosphere was used to increase the vacancies of oxygen in the crystalline structure. LTB:Cu [Formula: see text] PTFE (polytetrafluoroethylene) pellets were prepared by mixing the Li2B4O7:Cu with PTFE in a 4:1 ratio. The obtained materials were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). Crystals of Li2B4O7 with the average size of 134[Formula: see text]nm were obtained. The presence of copper was confirmed by SEM. The TL response of LTB:Cu PTFE pellets was studied with [Formula: see text] radiation by using a [Formula: see text]Co source. TTL response shows a linear behavior depending on the radiation dose. The effect of annealing time on TL glow curve was analyzed from 2[Formula: see text]h to 10[Formula: see text]h by irradiating with X-rays. The effect of mass on the TL response was studied varying the mass of the sample from 10[Formula: see text]mg to 50[Formula: see text]mg. From various heating rate studies, it was observed that the TL intensity increased when heating rate was gradually increased. The kinetic parameters were calculated by using computer deconvolution methods. The dosimetric property results showed that this material could have good potential application in a radiation dosimeter for radiation therapy treatment in the medical field.
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Journal of Molecular and Engineering Materials
Journal of Molecular and Engineering Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
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