台式近红外和微型近红外光谱仪对生姜及其不同加工程度产品质量控制的比较

IF 1.1 4区 化学 Q3 SPECTROSCOPY Spectroscopy Letters Pub Date : 2022-08-26 DOI:10.1080/00387010.2022.2116457
Yifan Zhang, Y. Zhang, Fei Sun, Yue Sun, Shumei Wang, J. Meng
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引用次数: 2

摘要

摘要干姜是姜的干燥根茎。姜炭(GC)是DG的加工品,由于加工程度难以控制,经常出现不合格的加工品(轻碳化姜、LCG;重碳化姜、HCG),这两者都会影响临床疗效。为了保证DG及其加工产品的质量和安全,本文主要研究了利用台式近红外光谱仪和微型近红外光谱仪快速测定DG及其加工品质量的可行性。分别用台式近红外光谱仪和微型近红外光谱仪对100个样品进行了扫描。通过不同的模型对收集的近红外光谱数据进行定性和定量分析。基于台式近红外光谱和微近红外光谱建立的偏最小二乘判别模型对预测集的判别率均为100%。使用三种特征波长选择方法(CARS、VCPA-IRIV和VCPA-GA)来提高偏最小二乘回归模型的性能。结果表明,CARS算法选择的波长的台式近红外模型表现最好,VCPA-IRIV算法选择的特征波长的Micro近红外模型性能具有较好的预测能力。对预测模型的一致性评价表明,除zingerone模型外,两种仪器具有很好的一致性。因此,微近红外光谱仪与适当的波长选择方法相结合,可以准确区分DG、LCG、MCG和HCG,并准确测定DG及其加工产品中的五种姜酚化合物。
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Comparison of benchtop near infrared and micro near infrared spectrometer for quality control of dried ginger and its different degrees of processed products
Abstract Dried ginger (DG) is the dried rhizome of Zingiber offcinale Rosc. (Fam. Zingiberaceae), Ginger charcoal (GC) is the processed products of DG, due to the difficulty in controlling the processing degree, unqualified processed products (light carbonized ginger, LCG; heavy carbonized ginger, HCG) often appear, which can both affect clinical efficacy. To ensure the quality and safety of DG and its processed products, this paper mainly focused on the feasibility of rapidly determining the quality of DG and its processed products by benchtop-NIR spectrometer and Micro-NIR spectrometer. A total of 100 samples were scanned by benchtop-NIR spectrometer and Micro-NIR spectrometer respectively. The collected NIRS data were qualitatively and quantitatively analyzed by different models. The partial least squares discriminant models established based on the benchtop-NIR and Micro-NIR spectroscopy both have a discrimination rate of 100% for the prediction set. Three characteristic wavelength selection methods (CARS, VCPA-IRIV and VCPA-GA) were used to improve the performance of partial least squares regression model. The results showed that the benchtop-NIR model with the wavelength selected by the CARS algorithm performed best, and the Micro-NIR model performance of the characteristic wavelength selected by the VCPA-IRIV algorithm had a better prediction ability. The consistency evaluation of the prediction models showed that the two instruments had a very good coherence except for the zingerone model. Therefore, A micro-NIR spectrometer combined with an appropriate wavelength selection method can precisely distinguish DG, LCG, MCG and HCG from each other and accurately determine the five gingerol compounds in DG and its processed products.
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来源期刊
Spectroscopy Letters
Spectroscopy Letters 物理-光谱学
CiteScore
2.90
自引率
5.90%
发文量
50
审稿时长
1.3 months
期刊介绍: Spectroscopy Letters provides vital coverage of all types of spectroscopy across all the disciplines where they are used—including novel work in fundamental spectroscopy, applications, diagnostics and instrumentation. The audience is intended to be all practicing spectroscopists across all scientific (and some engineering) disciplines, including: physics, chemistry, biology, instrumentation science, and pharmaceutical science.
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