H2SO4浓度和微波功率对微波辅助水解空棕榈果束生产糠醛的影响

Kusyanto Kusyanto, Suci Rahmadina
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引用次数: 1

摘要

空果串(EFB)是新鲜棕榈果串产生的废物,是棕榈油加工行业产生的有机废物之一,占总产量的23%。这种具有较高经济价值的废弃物,虽然已被用作锅炉燃料,但其利用仍不理想。事实上,如果进一步加工,EFB具有很高的经济价值。废渣可采用水解法处理,得到其戊聚糖含量,加入酸作为催化剂转化为糠醛。本研究的目的是找出最佳产率对硫酸浓度的影响,以及微波功率对EFB水解过程的影响。在此水解过程中,10克EFB加入250毫升硫酸,分别为3%、6%、9%、12%、15%、18%,微波功率分别为400W、600W、800W,加热75分钟。本研究采用气相色谱(GC)法测定糠醛含量。结果表明,当h2so4浓度为9%,微波功率为800W,浓度为0.39 mg/mL时糠醛含量最高,糠醛得率为0.9620%。
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The Effect of H2SO4 Concentration and Micro Wave Power in Microwave Assisted Hydrolysis of Furfural Production from Empty Palm Fruit Bunches
Empty fruit bunches (EFB), which are wastes from fresh palm fruit bunches, are one of organic wastes from palm oil processing industries as much as 23% of the total production. The utilization of this waste, which has a high economic value, is still not optimum although it has been used as a boiler fuel. In fact, EFB has a high economic value if processed further. The EFB as a waste can be processed using hydrolysis method to obtain its pentosan content and changed into furfural with the addition of acid as a catalyst. The objectives of this research are to find out the optimum yield on the sulfuric acid concentration and the effects of the power of microwaves used on hydrolysis process of EFB. On this hydrolysis process, 10 grams of  EFB was added with 250ml of sulfuric acid with the variations of 3%, 6%, 9%, 12%, 15%, and 18%, and microwave was used with the power variations of 400W, 600W, and 800W for 75 minutes. The analysis method used in this study to determine the furfural contentis Gas Chromatography (GC). The results showed the highest furfural content was obtained at H2SO4concentration of 9% with 800W power on the microwave and the concentration of 0.39 mg/mL and furfural yield of 0.9620%. 
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