ZnO纳米粉净化水溶液中孔雀绿染料

Pub Date : 2020-10-01 DOI:10.15251/jobm.2020.124.109
H. Idriss, A. Alakhras
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引用次数: 2

摘要

众所周知,孔雀石绿染料具有毒性致癌特性,即使在低浓度下也会对人类造成潜在的健康风险。因此,在排放到水体或水处理系统之前对染料进行修复是非常重要的。因此,本文演示了使用ZnO纳米粉末去除水相中孔雀石绿(MG)染料的清洁度。为了研究氧化锌纳米粉体对染料的去除效果,通过对接触时间、pH和初始染料浓度的影响进行了批量吸附实验。采用XRD、FTIR、SEM和EDX等多种技术对制备的纳米粉体进行了表征。结果表明,ZnO纳米粉体在脱色过程中具有快速的接触时间和初始浓度吸收特性。吸附剂的最大容量为246.36 mg。与其他吸附材料相比,ZnO纳米粉体对孔雀石绿染料是一种有效的吸附剂。吸附量和动力学参数及相关系数均符合Langmuir等温线模型R2(0.923)和拟二级动力学模型R2(0.994)。
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CLEAN UP OF MALACHITE GREEN DYE IN AQUEOUS SOLUTION USING ZnO NANOPOWDER
Malachite green dye has been known to have toxic carcinogenic characteristics and potential health risks for humans even at low concentrations. Hence, it is very vital to remediate the dye before discharge into water bodies or water treatment systems. Thus, this article demonstrated the removal of cleanup of malachite green (MG)dye from the aquatic phase using ZnO nanopowder. In this work batch adsorption experiments were accomplished as a function of contact time, pH, and initial dye concentration to study the efficiency of ZnO nanopowder on dye removal (MG). The obtained nanopowder was characterized using various techniques XRD, FTIR, SEM and EDX. The results shown that the maximum absorbed value was 233.16 mg / g. The findings show that ZnO nanopowder have fast contact time and initial concentration absorbing characteristics in dye removal. The maximum capacity of sorbent was found to be 246.36 mg. Furthermore, the study revealed that ZnO nanopowder is an effective sorbent for cleanup of malachite green dye in aqueous solution when comparing with other adsorbent materials. The Adsorption and kinetics parameters of the maximum capacity of sorbent and correlation coefficient showed that the data were well fitted the to the Langmuir isotherm R2 of 0.923 models and pseudo-second-order kinetic model with R2 of 0.994 respectively.
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