石墨烯纳米片增强高密度聚乙烯与黄麻织物的力学行为

U. O. Costa, Wendell Bruno Almeida Bezerra, Noemi Raquel Checca Huaman, S. Monteiro, Wagner Anacleto Pinheiro, Lúcio Fabio Cassiano Nascimento
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摘要

由于可持续的特性,天然木质纤维素纤维(FNL)和石墨烯纳米片(GNP)增强复合材料目前在广泛的工业领域中得到了应用。因此,在本工作中,研究了用0、0.10、0.25和0.50 wt.%的GNP和50 vol.%的Juta织物增强的高密度聚乙烯(HDPE)的机械和弯曲性能。特别是,Juta/HDPE/0.25%GNP复合材料的强度超过了文献中描述的强度,甚至有些复合材料的GNP更高。与不含GNP的Juta/HDPE复合材料相比,观察到复合材料的弯曲模量提高了38%。关于拉伸性能,与Juta/HDPE相比,Juta/HDPE/0.25%GNP的延展性提高了112%。此外,Juta/HDPE/0.25%GNP的韧性比Juta/HDPE复合材料高161%。断口的SEM分析表明,随着GNP浓度的升高,断裂机制从剪切带转变为纤颤、撕裂和龟裂的复杂混合物。因此,研究结果表明,新型Juta/HDPE/0.25%GNP纳米复合材料是一种很有前途的工程应用材料。
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MECHANICAL BEHAVIOR OF HIGH-DENSITY POLYETHYLENE REINFORCED WITH GRAPHENE NANOPLATELETS AND JUTE FABRIC
Owing to sustainable characteristics, natural lignocellulosic fibers (FNLs) and graphene nanoplatelets (GNP)-reinforced composites are currently seeing applications in a wide range of industrial fields. Thus, in the present work, the mechanical, and flexural properties of high-density polyethylene (HDPE) reinforced with 0, 0.10, 0.25, and 0.50 wt.% of GNP combined with 50 vol.% of Juta fabric were investigated. In particular, the Juta/HDPE/0.25%GNP composite outperformed the strength of those described in the literature, even some with higher GNP. Enhancements of 38% were observed for the composite’s flexural modulus as compared to the GNP-free Juta/HDPE composite. Regarding the tensile properties, the ductility of the Juta/HDPE/0.25%GNP was increased by 112% when compared to the Juta/HDPE. Moreover, the toughness of the Juta/HDPE/0.25%GNP was 161% superior to the Juta/HDPE composite. SEM analysis of the fracture surfaces showed that, as GNP concentration rises, the fracture mechanisms change from shear band to a complex mixture of fibrillation, tearing, and crazing. Consequently, the results reveal the novel Juta/HDPE/0.25%GNP nanocomposite as a promising material for engineering applications.
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