(μ1,以叔(dipheylphosphino)乙烷-κ2 P, P '] bis (3-mercapto-1 2-propanediolato -κ黄金(我))

IF 0.6 Q4 CHEMISTRY, ORGANIC Molbank Pub Date : 2023-07-19 DOI:10.3390/m1698

Taichi Baba, N. Yoshinari

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引用次数: 0

摘要

合成了一种新的双核金（I）配合物，该配合物具有桥接的二膦配体（1,2-双（二苯基膦基）乙烷）和两个末端巯基配体（1-硫代甘油），并通过IR、1H和31P NMR、荧光、ESI质量和漫反射光谱以及X射线衍射和元素分析进行了全面表征。该化合物通过晶体结构中的分子间亲金相互作用形成1D链超分子结构，导致固态光致发光。

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[μ-1,2-Bis(dipheylphosphino)ethane-κ2P,P’]bis(3-mercapto-1,2-propanediolato-κS-gold(I))

A new dinuclear gold(I) complex, possessing a bridging diphosphine ligand (1,2-bis(diphenylphosphino)ethane) and two terminal thiol ligands (1-thioglycerol), was synthesized and fully characterized by IR, 1H and 31P NMR, fluorescence, ESI-mass, and diffuse reflection spectroscopy, together with X-ray diffraction and elemental analyses. The compound formed a 1D chain supramolecular structure through intermolecular aurophilic interactions in the crystal structure, leading to photoluminescence in the solid state.

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来源期刊

Molbank Chemistry-Physical and Theoretical Chemistry

CiteScore

0.70

自引率

33.30%

发文量

174

审稿时长

11 weeks

期刊介绍： •organic synthesis •biosynthesis •extraction and purification •natural product derivatives •structural elucidation (X-ray crystallography, NMR, etc.)