蜡油混合物中蜡沉积的实验研究

Mojtaba Mansourpoor, Reza Azin, Shahriar Osfouri, Amir Abbas Izadpanah
{"title":"蜡油混合物中蜡沉积的实验研究","authors":"Mojtaba Mansourpoor,&nbsp;Reza Azin,&nbsp;Shahriar Osfouri,&nbsp;Amir Abbas Izadpanah","doi":"10.1007/s13203-019-0228-y","DOIUrl":null,"url":null,"abstract":"<p>Wax deposition is a common problem in oil pipelines and production systems. In this study, impact of water cut, mixing rate, chemical inhibitor, and time on wax deposition were investigated in a cold finger setup. Effect of different chemical inhibitors on wax appearance temperature (WAT) was studied using viscometry and differential scanning calorimetry techniques. Results suggested that WAT reduced with increasing inhibitor concentration, with 800?ppm being the optimum. Also, chloroform–toluene–ethylene vinyl acetate (EVA) mixture with 30, 30, and 40 wt% had the highest performance and reduced the WAT to 16.7?°C. Mixtures of toluene—EVA with acetone, p-xylene, and disulfide oil (DSO), followed next. Moreover, deposition decreased with increasing temperature difference between oil and pipe at constant cold surface temperature and increased upon increasing temperature difference at constant oil temperature. Wax deposition in two-phase system was lower than in single-phase system, but increased by increasing water cut. EVA–toluene, 2 wt% DSO, 2 wt% acetone, and 2 wt% p-xylene mixtures reduced the deposition to 23.33, 21.71, 32.14, and 12.5%, but addition of 2 wt% of EVA–DSO–acetone mixture reduced deposition to 35.74%. At similar operating conditions, flow turbulence has greater impact on reducing wax deposition, and its effect is enhanced using a proper inhibitor.</p>","PeriodicalId":472,"journal":{"name":"Applied Petrochemical Research","volume":"9 2","pages":"77 - 90"},"PeriodicalIF":0.1250,"publicationDate":"2019-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/s13203-019-0228-y","citationCount":"16","resultStr":"{\"title\":\"Experimental investigation of wax deposition from waxy oil mixtures\",\"authors\":\"Mojtaba Mansourpoor,&nbsp;Reza Azin,&nbsp;Shahriar Osfouri,&nbsp;Amir Abbas Izadpanah\",\"doi\":\"10.1007/s13203-019-0228-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Wax deposition is a common problem in oil pipelines and production systems. In this study, impact of water cut, mixing rate, chemical inhibitor, and time on wax deposition were investigated in a cold finger setup. Effect of different chemical inhibitors on wax appearance temperature (WAT) was studied using viscometry and differential scanning calorimetry techniques. Results suggested that WAT reduced with increasing inhibitor concentration, with 800?ppm being the optimum. Also, chloroform–toluene–ethylene vinyl acetate (EVA) mixture with 30, 30, and 40 wt% had the highest performance and reduced the WAT to 16.7?°C. Mixtures of toluene—EVA with acetone, p-xylene, and disulfide oil (DSO), followed next. Moreover, deposition decreased with increasing temperature difference between oil and pipe at constant cold surface temperature and increased upon increasing temperature difference at constant oil temperature. Wax deposition in two-phase system was lower than in single-phase system, but increased by increasing water cut. EVA–toluene, 2 wt% DSO, 2 wt% acetone, and 2 wt% p-xylene mixtures reduced the deposition to 23.33, 21.71, 32.14, and 12.5%, but addition of 2 wt% of EVA–DSO–acetone mixture reduced deposition to 35.74%. At similar operating conditions, flow turbulence has greater impact on reducing wax deposition, and its effect is enhanced using a proper inhibitor.</p>\",\"PeriodicalId\":472,\"journal\":{\"name\":\"Applied Petrochemical Research\",\"volume\":\"9 2\",\"pages\":\"77 - 90\"},\"PeriodicalIF\":0.1250,\"publicationDate\":\"2019-05-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1007/s13203-019-0228-y\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Petrochemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13203-019-0228-y\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Petrochemical Research","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s13203-019-0228-y","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 16

摘要

蜡沉积是石油管道和生产系统中常见的问题。在本研究中,在冷手指装置中研究了含水率、混合速率、化学抑制剂和时间对蜡沉积的影响。采用粘度法和差示扫描量热法研究了不同化学抑制剂对蜡表面温度的影响。结果表明WAT随抑制剂浓度的增加而降低,为800?PPM是最优的。此外,三氯甲烷-甲苯-乙烯乙酸乙烯(EVA)混合物的质量分数分别为30%、30%和40%,其性能最高,WAT降至16.7°C。接下来是甲苯- eva与丙酮、对二甲苯和二硫化油(DSO)的混合物。在冷表面温度恒定时,沉积随油与管道温差的增大而减小,随油与管道温差的增大而增大。两相体系的蜡沉积量低于单相体系,但随着含水率的增加而增加。eva -甲苯、2wt % DSO、2wt %丙酮和2wt %对二甲苯混合物的沉积率分别为23.33%、21.71%、32.14%和12.5%,而加入2wt % eva - DSO -丙酮混合物的沉积率分别为35.74%。在相同的操作条件下,流动湍流对减少蜡沉积的影响更大,使用合适的抑制剂可以增强其效果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Experimental investigation of wax deposition from waxy oil mixtures

Wax deposition is a common problem in oil pipelines and production systems. In this study, impact of water cut, mixing rate, chemical inhibitor, and time on wax deposition were investigated in a cold finger setup. Effect of different chemical inhibitors on wax appearance temperature (WAT) was studied using viscometry and differential scanning calorimetry techniques. Results suggested that WAT reduced with increasing inhibitor concentration, with 800?ppm being the optimum. Also, chloroform–toluene–ethylene vinyl acetate (EVA) mixture with 30, 30, and 40 wt% had the highest performance and reduced the WAT to 16.7?°C. Mixtures of toluene—EVA with acetone, p-xylene, and disulfide oil (DSO), followed next. Moreover, deposition decreased with increasing temperature difference between oil and pipe at constant cold surface temperature and increased upon increasing temperature difference at constant oil temperature. Wax deposition in two-phase system was lower than in single-phase system, but increased by increasing water cut. EVA–toluene, 2 wt% DSO, 2 wt% acetone, and 2 wt% p-xylene mixtures reduced the deposition to 23.33, 21.71, 32.14, and 12.5%, but addition of 2 wt% of EVA–DSO–acetone mixture reduced deposition to 35.74%. At similar operating conditions, flow turbulence has greater impact on reducing wax deposition, and its effect is enhanced using a proper inhibitor.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Applied Petrochemical Research
Applied Petrochemical Research ENGINEERING, CHEMICAL-
自引率
0.00%
发文量
0
审稿时长
13 weeks
期刊介绍: Applied Petrochemical Research is a quarterly Open Access journal supported by King Abdulaziz City for Science and Technology and all the manuscripts are single-blind peer-reviewed for scientific quality and acceptance. The article-processing charge (APC) for all authors is covered by KACST. Publication of original applied research on all aspects of the petrochemical industry focusing on new and smart technologies that allow the production of value-added end products in a cost-effective way. Topics of interest include: • Review of Petrochemical Processes • Reaction Engineering • Design • Catalysis • Pilot Plant and Production Studies • Synthesis As Applied to any of the following aspects of Petrochemical Research: -Feedstock Petrochemicals: Ethylene Production, Propylene Production, Butylene Production, Aromatics Production (Benzene, Toluene, Xylene etc...), Oxygenate Production (Methanol, Ethanol, Propanol etc…), Paraffins and Waxes. -Petrochemical Refining Processes: Cracking (Steam Cracking, Hydrocracking, Fluid Catalytic Cracking), Reforming and Aromatisation, Isomerisation Processes, Dimerization and Polymerization, Aromatic Alkylation, Oxidation Processes, Hydrogenation and Dehydrogenation. -Products: Polymers and Plastics, Lubricants, Speciality and Fine Chemicals (Adhesives, Fragrances, Flavours etc...), Fibres, Pharmaceuticals.
期刊最新文献
Applied petrochemical research: final issue La-Faujasite zeolite activated with boron trifluoride: synthesis and application as solid acid catalyst for isobutane–isobutene alkylation Evaluation of hybrid solvents featuring choline chloride-based deep eutectic solvents and ethanol as extractants for the liquid–liquid extraction of benzene from n-hexane: towards a green and sustainable paradigm Trending approaches on demulsification of crude oil in the petroleum industry Synthesis and study of aroylethyl(ethyl)-xanthates as stabilizers of polymeric materials
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1