(Al2O3)纳米粒子的加入对Bi2Ba2Ca2Cu3O10“+δ”超导体高温结构和电性能的影响

Fouad Kamal Tawfeeq Alsumaidaei, H. Mohammed
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引用次数: 1

摘要

为了增强材料的超导体结构特性,研究人员在样品中加入了纳米氧化铝。采用固相反应法制备了X=(0 ~ 0.9)的高温超导体1x (Bi2Ba2Ca2Cu3O10+) + X(Al2O3)样品,压力为8吨/厘米2,退火温度为800。电学性能表明,样品的Tc从126k增加到139k,样品中的氧含量也随着X值从0增加到0.5而增加,而tcd在X值大于0.5时随X值的增加而增加,小于77k。在结构性能方面,样品的X射线衍射表现为正交相,在X=0时a=4.286A, b=5.4184A, c=35.3528A,在X=0.5时c值增加到35.9848A。AFM结果表明,在X=0.5时,最佳样品的平均晶粒尺寸为47.67 nm。扫描电镜显示,根据原子量不同,有与Bi、Cu等较重元素相关的暗区和与Ba、Ca等较轻元素相关的亮区
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The Effect of Addition of (Al2O3) Nano Particles on Structural and Electrical Properties of Bi2Ba2Ca2Cu3O10" +δ" Superconductors at High Temperature
To enhancement the superconductor structural characteristics, nanoparticles of the Al 2O3 were added to the samples under study. The Samples of high temperature superconductors 1 X (Bi2Ba2Ca2Cu3O10+ ) + X(Al2O3) with X= (0-0.9) were prepared by solid state reaction method under hydraulic pressure 8 ton/cm 2 and annealing temperature 800. Electrical properties of the samples showed that Tc increases from 12 6 K to 139 K, and also oxygen content in samples increased with increasing X values from 0 to 0.5, while T c d creased less than 77 K with increasing X at values more than 0.5. In Structural properties, the X -ray diffraction of the samples showed orthorhombic phase wi th a=4.286A, b=5.4184A, c=35.3528A at X=0, while c-value is increased to 35.9848A at X=0.5. AFM results shows that the average grain size of the best sample was 47.67 nm at X=0.5. SEM it showed that there are dark regions related to the heav ier elements, such as Bi and Cu , and light regi ons related to lighter elements , uch as Ba and Ca , depending on atomic weights
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