提高电工钢绝缘性能的有机-无机杂化涂层的制备与表征

IF 2.3 4区 材料科学 Q2 Chemistry Journal of Coatings Technology and Research Pub Date : 2023-03-15 DOI:10.1007/s11998-022-00751-6
Bong-Gu Kim, Hyun-Hee Choi, Hye-Yeong Park, Min Serk Kwon, Yun-Ki Byeun, Sung Kang, Yeon-Gil Jung, Jung-Hun Son, SeungCheol Yang
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引用次数: 0

摘要

磷酸盐由于其优异的电绝缘性和耐腐蚀性,已被用作各种领域的涂覆剂,如电工钢(ES)。尽管磷酸盐涂层的绝缘性能可以显著改善ES板的铁损,但仍需开发新的涂层材料来进一步提高ES板的性能。在本研究中,我们合成了有机-无机杂化包衣剂,与传统的磷酸盐包衣剂相比,它具有更好的绝缘性。以绝缘性能优良的无机颗粒(SiO2、TiO2和Cr2O3)和硅烷偶联剂为原料。涂覆剂中适当溶剂含量的硅烷偶联剂对无机颗粒进行了良好的表面改性,使涂覆剂具有良好的分散稳定性。涂覆剂分散均匀是由于涂覆在ES上的杂化材料具有良好的表面粗糙度。最后,将优化组合后的杂化涂覆剂应用于ES时,其绝缘性能(< 100 mA)优于常规磷酸盐涂层(~ 200 mA),耐腐蚀性能也很好。
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Preparation and characterization of organic–inorganic hybrid coatings for improving the insulation properties of electrical steel

Phosphate has been used as a coating agent in various fields, such as electrical steel (ES), because of its excellent electrical insulation and corrosion resistance. Although the insulating properties of a phosphate coating can significantly improve the iron loss of the ES sheet, a new coating material to enhance the performance of the ES sheet further should be developed. In this study, we synthesized organic–inorganic hybrid coating agents with superior insulation compared to that of the conventional phosphate coating agent. Inorganic particles with excellent insulating properties (SiO2, TiO2, and Cr2O3) and silane coupling agents were used as starting materials. The good surface modification of inorganic particles by silane coupling agents with appropriate solvent content in the coating agent led to good dispersion stability of the coating agent. Homogeneous dispersion of the coating agent was attributed to the good surface roughness of the hybrid materials coated on the ES. Finally, when the hybrid coating agent with optimized composition was applied to the ES, the insulation property of the hybrid coating (< 100 mA) was superior compared to that of the conventional phosphate coating (~ 200 mA), and corrosion resistance was also excellent.

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来源期刊
Journal of Coatings Technology and Research
Journal of Coatings Technology and Research CHEMISTRY, APPLIED-MATERIALS SCIENCE, COATINGS & FILMS
CiteScore
4.40
自引率
8.70%
发文量
0
期刊介绍: Journal of Coatings Technology and Research (JCTR) is a forum for the exchange of research, experience, knowledge and ideas among those with a professional interest in the science, technology and manufacture of functional, protective and decorative coatings including paints, inks and related coatings and their raw materials, and similar topics.
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