铈和钛对NiMn2O4选择性NH3催化还原NO的促进作用

IF 1.6 4区 工程技术 Q3 Chemical Engineering International Journal of Chemical Reactor Engineering Pub Date : 2022-11-04 DOI:10.1515/ijcre-2022-0072
Sara Karkhaneh, Seyed Mahdi Latifi, E. Kashi, A. Salehirad
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引用次数: 0

摘要

摘要采用共沉淀法制备了NiMn2O4、NiMn2O4/TiO2和NiMn2O4/CeO2纳米复合材料,并对NH3选择性催化还原NOx的性能进行了评价。采用x射线衍射、场发射扫描电镜、比表面积、平均孔径、程序升温解吸(NH3-TPD)、程序升温还原(H2-TPR)、电感耦合等离子体发射光谱仪等多种表征方法对催化剂的理化性质进行了表征。催化活性测试表明,在200 ~ 400℃的温度窗和10000 ~ 40000 h−1的空速范围内,NiMn2O4/CeO2在合成的催化剂中表现出最好的催化性能。
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Promotional effects of cerium and titanium on NiMn2O4 for selective catalytic reduction of NO by NH3
Abstract In this work NiMn2O4, NiMn2O4/TiO2 and NiMn2O4/CeO2 nanocomposites were prepared by co-precipitation method and evaluated for the selective catalytic reduction of NOx with NH3. Various characterization methods such as X-ray diffraction, field emission scanning electron microscope, specific surface area, average pore diameter, temperature programmed desorption (NH3-TPD), temperature-programmed reduction (H2-TPR) and inductively coupled plasma optical emission spectrometer were conducted to probe the physical and chemical properties of these catalysts. The catalytic activity tests showed that in the temperature window of 200–400 °C and the space velocity of 10,000–40,000 h−1, NiMn2O4/CeO2 demonstrated the best performance among the synthesized catalysts.
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来源期刊
CiteScore
2.80
自引率
12.50%
发文量
107
审稿时长
3 months
期刊介绍: The International Journal of Chemical Reactor Engineering covers the broad fields of theoretical and applied reactor engineering. The IJCRE covers topics drawn from the substantial areas of overlap between catalysis, reaction and reactor engineering. The journal is presently edited by Hugo de Lasa and Charles Xu, counting with an impressive list of Editorial Board leading specialists in chemical reactor engineering. Authors include notable international professors and R&D industry leaders.
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