中性原子小分子气相解离过程的第一步:偶奇规则和有机和无机原子特定元素周期表的应用

G. Auvert
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引用次数: 1

摘要

小分子在气相中的离解已被深入研究,各种气体的离解能可在参考文献中获得。化合物在离解前后的构型通常是已知的,但局部电荷没有定义。基于奇偶规则,这是同一作者之前一系列文章的主题,本文的目的是展示如何使用它来给出气体离解的电子规则。为此,创建并使用了一个特定的周期表。这些规则被应用于30多种常见分子的选择,表明奇偶规则及其结果有助于解释气体中的离解现象。
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First Step in Dissociation Process in the Gas Phase for Small Molecules with Neutral Atoms: Application with the Even-Odd Rule and a Specific Periodic Table for Organic and Inorganic Atoms
Dissociations in the gas phase of small molecules have been intensively studied and dissociation energies of various gases are available in reference works. Configurations of compounds before and after the dissociation are usually known, but local charges are not defined. Building on the even-odd rule, the topic of a series of previous articles by the same author, the objective of this paper is to show how it can be used to give electronic rules for dissociations in gases. To this end, a specific periodic table is created and used. The rules are applied to a selection of more than 30 common molecules, showing that the even-odd rule and its consequences are useful in explaining the phenomenon of dissociation in gases.
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