过渡金属氧化物基催化剂在水氧化阳极生成过氧化氢中的应用

IF 0.7 4区 材料科学 Q4 ELECTROCHEMISTRY Journal of New Materials For Electrochemical Systems Pub Date : 2022-12-31 DOI:10.14447/jnmes.v25i4.a03
Areej Alzahrani, S. Hassan, M. H. Nazir, A. Zafar, S. Zaidi
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引用次数: 0

摘要

水的氧化可能有助于通过电化学途径生成有用的氧化剂过氧化氢(H2O2)。在PV-15复合涂层上进行热压缩处理,合成了一种结构明确的氧化钼基电极。然后,该涂层用于恒电位电解的电化学水分解,同时在先进类型的电池组件中测量产生的过氧化氢的数量。总体研究结果表明,H2O2生产的应用电位限制值为+0.3 V、+0.4 V和+0.5 V,相对于Hg/HgO,在先进类型的电池组件中合成的过氧化氢高达13 ppm。
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Water Oxidation for Anodic Generation of Hydrogen Peroxide by Using Transition Metal Oxide Based Catalyst
Water oxidation could be helpful to have a generation of useful oxidant known as hydrogen peroxide (H2O2) via electrochemical route. A defined structured of molybdenum oxide based electrode was synthesised by a thermal compression treatment over PV-15 composite coating. The coating was then employed for electrochemical water splitting at constant potential electrolysis while the quantities of peroxide of hydrogen produced was measured in an advanced type of cell assembly. The overall findings showed that the confined values of applied potential for H2O2 production are anodic constant potentials of +0.3 V, +0.4 V and +0.5 V vs. Hg/HgO and synthesised peroxide of hydrogen up to 13 ppm in an advanced type of cell assembly.
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来源期刊
Journal of New Materials For Electrochemical Systems
Journal of New Materials For Electrochemical Systems ELECTROCHEMISTRY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
1.90
自引率
0.00%
发文量
33
审稿时长
>12 weeks
期刊介绍: This international Journal is intended for the publication of original work, both analytical and experimental, and of reviews and commercial aspects related to the field of New Materials for Electrochemical Systems. The emphasis will be on research both of a fundamental and an applied nature in various aspects of the development of new materials in electrochemical systems.
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