超声作用强度对硫酸钙杂质中卤石废渣净化程度的影响

Olga E. Nisina, S. V. Lanovetskiy, O. Kosvintsev
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引用次数: 0

摘要

在钾镁矿的富集过程中,形成了数百万吨的固体卤石废物,占据了广阔的土地,对环境构成了威胁。这两种废物的主要有用成分是氯化钠,在许多化学工业中用作原料。最常见的加工生产线是生产技术型氯化钠和技术型氯化钠溶液。这些产品是中间体,可用于进一步的化学工艺。由于杂质的存在,如CaSO4、MgCl2、不溶性残留物等,阻碍了这些产品达到所需质量。最不希望的杂质是硫酸钙,其浓度可达3%。根据文献资料,确定了水分散介质超声处理的最佳强度。介绍了岩盐固体废物(采石场盐和岩盐排土场)的物相和颗粒组成分析结果。揭示了岩盐废料晶体中硫酸钙杂质的分布特征。本文考察了超声处理强度对岩盐废渣中硫酸钙残留量影响的研究结果。在研究结果的基础上,确定了超声作用的持续时间和强度,在此条件下得到的卤石原料中硫酸钙的最低浓度。所获得的结果允许建立清洗卤石原料过程的最佳制度(超声波作用强度,处理时间),这使得在机械清洗阶段显著减少硫酸钙的含量,并证实了利用所获得的结果改进氯化钠技术溶液生产技术的潜在可能性,由氯化钾“乌拉尔”产生的固体卤石废物。
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INFLUENCE OF INTENSITY OF ULTRASONIC ACTION ON DEGREE OF PURIFICATION OF HALITE WASTE FROM CALCIUM SULPHATE IMPURITY
When enriching potassium-magnesium ores, millions of tons of solid halite waste are formed, occupying vast areas and posing a danger to the environment. The main useful component of both these wastes is sodium chloride, which serves as a raw material in many chemical industries. The most common processing lines are the production of technical sodium chloride and technical sodium chloride solution. These products are intermediate and can be used in further chemical processes. Obtaining these products of the required quality is hindered by the presence of impurities, such as CaSO4, MgCl2, insoluble residues. The most undesirable impurity is calcium sulphate, the concentration of which can reach 3%. According to the literature sources, the optimal intensity of ultrasonic treatment of the water-dispersed medium was determined. The results of analyzes of phase and granulometric composition of solid halite waste (quarry salt and halite dump) are presented. The character of distribution of calcium sulfate impurity in crystals of halite waste is revealed. The article examines the results of the study of the influence of the intensity of ultrasonic treatment on the residual content of calcium sulphate in halite waste. Based on the results of the studies, the duration and intensity of the ultrasonic effect were established, at which the minimum concentration of calcium sulfate in the resulting halite raw material is reached. The obtained results allowed to establish the optimal regime of the process of cleaning the halite raw materials (intensity of ultrasonic action, processing time), which allow to significantly reduce the content of calcium sulphate during the mechanical cleaning stage and confirmed the potential possibility of using the obtained results for improving the technology of sodium chloride technical solution production, solid halite waste produced by potassium chloride "Uralkali".
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来源期刊
CiteScore
1.40
自引率
44.40%
发文量
83
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