{"title":"EmimCl和BmimPF6离子液体在最佳电解质组合条件下在有限温度范围（25至75°C）下的电导率","authors":"M. Sarwar, Hanhui Zhan, Jiaxin Yang","doi":"10.21743/pjaec/2020.12.39","DOIUrl":null,"url":null,"abstract":"The purpose of this study was to evaluate the ionic conductivity as a function of temperature, range (25 to 75°C) in the imidazolium-based ionic liquids 1-ethyl-3-methylimidazolium chloride (EmimCl) and 1-butyl-3-methyl imidazolium hexafluorophosphate (BmimPF6) of different volume percentages under optimal electrolyte combination conditions. The findings revealed that when 1% EmimCl or 1% BmimPF6 was applied, conductivity decreased significantly in relation to the Kohlrausch relationship. When 1% EmimCl or 2% BmimPF6 was added, the study showed the highest coefficient of alpha (α), while beta (β) was the lowest coefficient for temperature. In conclusion, the influence of the change in volume percentage on the conductivity is weakened by temperature control.","PeriodicalId":19846,"journal":{"name":"Pakistan Journal of Analytical & Environmental Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4000,"publicationDate":"2020-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Conductivity of EmimCl and BmimPF6 Ionic Liquids for Limited Range of Temperature (25 to 75 °C) Under Optimal Electrolyte Combination Conditions\",\"authors\":\"M. Sarwar, Hanhui Zhan, Jiaxin Yang\",\"doi\":\"10.21743/pjaec/2020.12.39\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The purpose of this study was to evaluate the ionic conductivity as a function of temperature, range (25 to 75°C) in the imidazolium-based ionic liquids 1-ethyl-3-methylimidazolium chloride (EmimCl) and 1-butyl-3-methyl imidazolium hexafluorophosphate (BmimPF6) of different volume percentages under optimal electrolyte combination conditions. The findings revealed that when 1% EmimCl or 1% BmimPF6 was applied, conductivity decreased significantly in relation to the Kohlrausch relationship. When 1% EmimCl or 2% BmimPF6 was added, the study showed the highest coefficient of alpha (α), while beta (β) was the lowest coefficient for temperature. In conclusion, the influence of the change in volume percentage on the conductivity is weakened by temperature control.\",\"PeriodicalId\":19846,\"journal\":{\"name\":\"Pakistan Journal of Analytical & Environmental Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2020-12-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Pakistan Journal of Analytical & Environmental Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21743/pjaec/2020.12.39\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Pakistan Journal of Analytical & Environmental Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21743/pjaec/2020.12.39","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
The Conductivity of EmimCl and BmimPF6 Ionic Liquids for Limited Range of Temperature (25 to 75 °C) Under Optimal Electrolyte Combination Conditions
The purpose of this study was to evaluate the ionic conductivity as a function of temperature, range (25 to 75°C) in the imidazolium-based ionic liquids 1-ethyl-3-methylimidazolium chloride (EmimCl) and 1-butyl-3-methyl imidazolium hexafluorophosphate (BmimPF6) of different volume percentages under optimal electrolyte combination conditions. The findings revealed that when 1% EmimCl or 1% BmimPF6 was applied, conductivity decreased significantly in relation to the Kohlrausch relationship. When 1% EmimCl or 2% BmimPF6 was added, the study showed the highest coefficient of alpha (α), while beta (β) was the lowest coefficient for temperature. In conclusion, the influence of the change in volume percentage on the conductivity is weakened by temperature control.
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