用深共晶溶剂制备了金纳米颗粒,并将其用作表面增强拉曼散射的衬底

IF 2.1 4区 工程技术 Q3 CHEMISTRY, INORGANIC & NUCLEAR Gold Bulletin Pub Date : 2023-01-17 DOI:10.1007/s13404-022-00324-w
Tao Wang, Qian Liu, Minshan Shi, Rong Chang, Jun Tang, Yalan He, Dongling Wu
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引用次数: 1

摘要

摘要在深度共晶溶剂(DES)中制备了具有高增强活性的荔枝状金纳米粒子(Au NPs),并以罗丹明6G (R6G)为探针分子进行检测,所制备的金纳米粒子作为SERS活性底物表现出优异的灵敏度。计算得到增强因子(EF)约为1.8 × 1012,在10 ~ 12 m的R6G水溶液中最低检测浓度突出。此外,利用所制备的Au NPs成功地测定了新疆产骆驼奶粉中青霉素G钠(PG)的微量含量。本研究为制备高效、灵敏的表面增强拉曼散射(SERS)材料提供了一种环保、简单、快速的方法。同时,也为以DES为反应溶液制备SERS提供了一种新的可能性。图形抽象
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Gold nanoparticles prepared with the aid of deep eutectic solvent and used as substrates for surface-enhanced Raman scattering

Abstract

The high enhancement activity of litchi-like gold nanoparticles (Au NPs) is prepared in deep eutectic solvent (DES), and the prepared Au NPs as SERS active substrate exhibits excellent sensitivity when rhodamine 6G (R6G) is used as a probe molecule for detection. The enhancement factor (EF) is calculated to be about 1.8 × 1012, and the minimum detected concentration is outstanding in R6G aqueous solution at 10−12 M. In addition, the microtrace determination of penicillin G sodium (PG) in camel milk powder produced in Xinjiang was successfully achieved by using the prepared Au NPs. This work provides an environmentally friendly, simple, and rapid method to prepare efficient and sensitive surface-enhanced Raman scattering (SERS) materials. Meanwhile, it also uncovers a new possibility for the development of various nanoparticles with SERS prepared using DES as reactive solutions.

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来源期刊
Gold Bulletin
Gold Bulletin Chemistry-Inorganic Chemistry
CiteScore
3.70
自引率
4.50%
发文量
21
期刊介绍: Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.
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