甲烷氧化二聚反应生成c2烃

D.B. Augaliev, M. Erkibaeva, A. Aidarova, S. Tungatarova, T. Baizhumanova
{"title":"甲烷氧化二聚反应生成c2烃","authors":"D.B. Augaliev, M. Erkibaeva, A. Aidarova, S. Tungatarova, T. Baizhumanova","doi":"10.32014/2021.2518-1491.44","DOIUrl":null,"url":null,"abstract":"The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.","PeriodicalId":43167,"journal":{"name":"News of the National Academy of Sciences of the Republic of Kazakhstan-Series Chemistry and Technology","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2021-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"OXIDATIVE DIMERIZATION OF METHANE TO C2 HYDROCARBONS\",\"authors\":\"D.B. Augaliev, M. Erkibaeva, A. Aidarova, S. Tungatarova, T. Baizhumanova\",\"doi\":\"10.32014/2021.2518-1491.44\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.\",\"PeriodicalId\":43167,\"journal\":{\"name\":\"News of the National Academy of Sciences of the Republic of Kazakhstan-Series Chemistry and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"News of the National Academy of Sciences of the Republic of Kazakhstan-Series Chemistry and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32014/2021.2518-1491.44\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"News of the National Academy of Sciences of the Republic of Kazakhstan-Series Chemistry and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32014/2021.2518-1491.44","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5

摘要

由于最现代技术的不断生产和加工,世界石油储量每天都在减少。全世界的科学家都在寻找各种原料和方法,利用丰富的天然气资源来替代石化产品。在这方面,天然气作为石油化学工业的一种替代原料来源受到了极大的关注。研究了SHS法制备的新型20%La-10%Ce20%Mg-50%甘氨酸催化剂上的甲烷脱氢反应,确定了其最佳制备条件、金属的浓度和配比,以及接触时间和工艺温度对反应方向和机理的影响。介绍了甲烷氧化脱氢制C2烃过程中采用SHS法制备的20% La-10% Ce-20% Mg-50%甘氨酸催化剂的研究结果。在实验研究的基础上,发现在找到的最佳条件下,催化剂的组成在上述反应中表现出较高的活性。由此确定了反应温度对甲烷氧化转化催化剂组成的影响,选择生成乙烷和乙烯的最佳温度为T=700o С。结果表明,CH4:O2: Ar混合物在C2烃中选择性氧化的最佳条件为:T=700o С, CH4:O2=2,5:1, 5000 h-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
OXIDATIVE DIMERIZATION OF METHANE TO C2 HYDROCARBONS
The world's oil reserves are decreasing every day due to the continuous production and processing of the most modern technologies. Scientists all over the world are looking for various raw materials and methods to use the vast resources of natural gas as a substitute for petrochemicals. In this regard, great attention is drawn to natural gas as an alternative source of raw materials for petrochemical industries. The purpose of this work is to study the reaction of methane dehydrogenation on new 20%La-10%Ce20%Mg-50% glycine catalysts prepared by the SHS method to identify the optimal conditions for their preparation, concentration and ratio of metals, the influence of contact time and process temperature on the direction and mechanism of the reaction. The results of the study of 20% La-10% Ce-20% Mg-50% glycine catalyst prepared by the SHS method in the process of oxidative dehydrogenation of methane into C2 hydrocarbons are presented. On the basis of experimental studies, it was found that the composition of the catalyst exhibits high activity in the above reaction under the found optimal conditions. Thus, the influence of reaction temperature on the developed composition of catalysts for oxidative conversion of methane has been determined that the optimum temperature for the selective formation of ethane and ethylene is T=700o С. It was found that for selective oxidation of a mixture of CH4: O2 : Ar in C2 hydrocarbons the optimal conditions are: T=700o С, CH4:O2=2,5:1, 5000 h-1.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
24
期刊最新文献
DETERMINATION OF LITHIUM CONCENTRATION IN INDUSTRIAL WATERS OF SHU-SARYSU PROVINCE BY ELECTROPHORESIS METHOD THE ROLE OF DEPOLARIZERS IN THE PROCESSES OF HYDROGEN RELEASE FROM WATER ON THE ALUMINUM AMALGAM SURFACE DESCRIPTION OF NONLINEAR OSCILLATIONS OF A PERTURBED FILM IN ITS COLLISION WITH LIQUID DROPS APPLICATION OF BENTONITE CLAY AS A PROTECTIVE BARRIER IN THE DISPOSAL OF RADIOACTIVE WASTE OF NUCLEAR INDUSTRY OF KAZAKHSTAN PREPARATION AND PHYSICO–CHEMICAL CHARACTERIZATION OF ORGANICALLY MODIFIED CLAYS WITH GRAFTED DMSO AND TEOA
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1