电液对高树脂油“卡拉赞巴斯”理化特性影响的研究

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY Eurasian Chemico-Technological Journal Pub Date : 2020-12-28 DOI:10.18321/ectj999
R. Salakhov, M. Seitzhanova, D. U. Bodykov, Larissa R. Sassykova, N. Zhakirova, T. Seilkhanov
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引用次数: 1

摘要

为了改变哈萨克斯坦卡拉詹巴斯油田高树脂油的粘度,研究了电液作用对粘度的影响。研究了添加有机溶剂二甲苯对油流变性能的影响。采用气相色谱-质谱联用技术对电液冲击前后油品的碳氢化合物组成进行了对比研究。通过1H和13C NMR光谱测定了电液处理前后油烃的碎片组成。结果表明,重油馏分向轻质馏分的转化始于五次电液冲击。确定20-25个放电脉冲足以用于分解碳氢化合物的定量过程。研究发现,在电液作用下,向高粘度油中加入二甲苯会增加碳氢化合物的转化率。在电液处理过程中,高粘度油中链烷烃和萘的含量略有降低。在油中,在电液作用后,观察到烃的长烷基末端СН3-基团的质子比例下降,这表明重油馏分分解为轻馏分的过程。
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Investigation of Electrohydraulic Effect on Physicochemical Characteristics of High-Resinous Oil “Karazhanbas”
In order to change the viscosity of high-resinous oil of the “Karazhanbas” field (Kazakhstan), the effect of electrohydraulic action on it was studied. The effect of adding an organic solvent xylene on the rheological properties of oil is investigated. A comparative study of the hydrocarbon composition of oil before and after electrohydraulic impact was carried out by the method of gas chromatographymass spectrometry. Fragment composition of oil hydrocarbons before and after electrohydraulic treatment was determined by 1H and 13C NMR spectroscopy. It is shown that the conversion of heavy oil fractions to light ones begins with a five-time electrohydraulic impact. It is determined that 20‒25 electric discharge pulses are sufficient for the quantitative process of splitting hydrocarbons. It was found that the addition of xylene to high-viscosity oil leads to an increase in the conversion of hydrocarbons under electrohydraulic action. The content of paraffins and naphthalenes in high-viscosity oil is slightly reduced during electrohydraulic processing. In oil, after electrohydraulic action, a decrease in the proportion of protons of long alkyl terminal СН3-groups of hydrocarbons is observed, which indicates the process of decomposition of heavy oil fractions into light fractions.
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来源期刊
Eurasian Chemico-Technological Journal
Eurasian Chemico-Technological Journal CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.10
自引率
20.00%
发文量
6
审稿时长
20 weeks
期刊介绍: The journal is designed for publication of experimental and theoretical investigation results in the field of chemistry and chemical technology. Among priority fields that emphasized by chemical science are as follows: advanced materials and chemical technologies, current issues of organic synthesis and chemistry of natural compounds, physical chemistry, chemical physics, electro-photo-radiative-plasma chemistry, colloids, nanotechnologies, catalysis and surface-active materials, polymers, biochemistry.
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