从电子垃圾中回收丙烯腈-丁二烯-苯乙烯,用于生产3D打印的环保灯丝

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-06-18 eCollection Date: 2024-06-01 DOI:10.1089/3dp.2022.0211
Rafaela de Oliveira, Milena Heloísa Araújo Silva, Pankaj Agrawal, Gustavo de Figueiredo Brito, Carlos Thiago Candido Cunha, Tomás Jeferson Alves de Mélo
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引用次数: 0

摘要

在这项工作中,利用电子废弃物(e-waste)中的丙烯腈-丁二烯-苯乙烯(ABS)共聚物来生产应用于 3D 打印的长丝。电子废弃物中的回收 ABS(rABS)与原生 ABS(vABS)以不同浓度混合。通过差示扫描量热法观察到,vABS/rABS 混合物的玻璃化转变温度值介于 vABS 和 rABS 的玻璃化转变温度值之间。扭矩流变分析表明,添加 rABS 后 vABS 的加工性没有受到影响。流变测量结果表明,在低频下,vABS 的粘度高于 rABS,这表明 vABS 和 rABS 是不相溶的。三维打印样品的冲击强度(IS)测试表明,随着 rABS 含量的增加,IS 也在增加,最高可达 50 wt%。将 vABS 与电子废弃物中的 rABS 混合是很有前景的,而且证明是可行的,这使得从电子废弃物中回收大量塑料成为可能,从而为保护环境做出了贡献。
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Recycling of Acrylonitrile Butadiene Styrene from Electronic Waste for the Production of Eco-Friendly Filaments for 3D Printing.

In this work, acrylonitrile butadiene styrene (ABS) copolymer from electronic waste (e-waste) was used to produce filaments for application in 3D printing. Recycled ABS (rABS) from e-waste was blended with virgin ABS (vABS) in different concentrations. By differential scanning calorimetry, it was observed that the values of the glass transition temperatures for vABS/rABS blends ranged between the values of vABS and rABS. Torque rheometry analysis showed that the processability of vABS was not compromised with the addition of rABS. Rheological measurements showed that the viscosity of vABS was higher than that of rABS at low frequencies and indicated that vABS and rABS are immiscible. Impact strength (IS) tests of the 3D printed samples showed an increase in the IS with an increase in the rABS content up to 50 wt%. Blending vABS with rABS from e-waste is promising and proved to be feasible, making it possible to recycle a considerable amount of plastics from e-waste and, thus, contributing to the preservation of the environment.

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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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