从环境安全的角度谈灰渣在公路建设中的应用

O. Krainiuk, Y. Buts, P. Lotsman, V. Barbashyn
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引用次数: 0

摘要

探讨了在道路建设中利用火电厂灰渣和粉煤灰作为工业废弃物处理方式之一的实践。本研究的目的是确定TPP灰渣的化学成分,研究其作为道路建设原料的可能性。为实现这一目标,确定了以下任务:确定火电厂灰和灰渣的主要物理化学性质,并对这些废物在道路建设中的利用进行环境评价。对Zmievskaya、Krivorozhskaya、Trypilskaya、Slavyanskaya电厂的灰渣进行了化学分析,确定了主要成分:SiO2、Al2O3、Fe2O3、CaO、MgO、SO3、Nа2О和К2О。用原子吸收法测定了样品中重金属的含量。采用浓度-对数图的构造方法,研究了道路施工过程中灰渣路面重金属化合物的迁移能力。为了预测重金属化合物在道路建设中向环境中的迁移,绘制了最可能离子(例如,铜)[Cu(OH)n 2-n]的浓度与环境pH值的独立关系。铜化合物在中性和碱性环境中不迁移已被证明,这使得它们的使用安全。对其他金属也进行了类似的计算。
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THE USE OF ASH AND SLAG IN ROAD CONSTRUCTION IN THE POSITION OF ENVIRONMENTAL SAFETY
This paper explores the practice of using ash and slag and fly ash from thermal power plants in road construction as one of the ways to dispose of industrial waste. The purpose of the study is to determine the chemica l composition of TPP ash and slag to study the possibility of using it as a raw material for road construction. To achieve the goal, the following tasks were set: to determine the main physical and chemical properties of ash and ash and slag from thermal power plants, to give an environmental assessment of the use of these wastes in road construction. Chemical analysis of ash and slag from Zmievskaya, Krivorozhskaya, Trypilskaya, Slavyanskaya TPPs was carried out to determine the main components: SiO2, Al2O3, Fe2O3, CaO, MgO, SO3, Nа2О and К2О. The content of heavy metals was determined using the method of atomic absorption analysis. The migration ability of heavy metal compounds from the roadway using ash and slag in the construction of roads has been studied using the construction of concentration-logarithmic diagrams. To predict the migration of heavy metal compounds into the environment when they are used in road construction, a separate dependence of the concentration of the most probable ions was plotted (for example, cuprum) [Cu(OH)n 2-n] on the pH of the environment. The lack of migration of cuprum compounds in a neutral and alkaline environment has been proven, which makes their use safe. Similar calculations were made for other metals.
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发文量
28
审稿时长
27 weeks
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